JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Critical Thinking Electrochemistry

  • question_answer
    The limiting molar conductivities \[{{\wedge }^{0}}\]for NaCl, KBr and KCl are 126, 152 and 150 \[S\ c{{m}^{2}}mo{{l}^{-1}}\] respectively. The \[{{\wedge }^{0}}\] for NaBr is                                    [AIEEE 2004]

    A)                 \[278\ S\ c{{m}^{2}}mo{{l}^{-1}}\]           

    B)                 \[176\ S\ c{{m}^{2}}mo{{l}^{-1}}\]

    C)                 \[128\ S\ c{{m}^{2}}mo{{l}^{-1}}\]           

    D)                 \[302\ S\ c{{m}^{2}}mo{{l}^{-1}}\]

    Correct Answer: C

    Solution :

               \[(126\ sc{{m}^{2}})\wedge _{NaCl}^{0}\ =\ \wedge _{N{{a}^{+}}}^{0}+\wedge _{C{{l}^{-}}}^{0}\]                          .....(1)                    \[(152\ sc{{m}^{2}})\wedge _{KBr}^{0}\ =\ \wedge _{{{K}^{+}}}^{0}+\wedge _{B{{r}^{-}}}^{0}\]                       .....(2)                    \[(150\ sc{{m}^{2}})\wedge _{KCl}^{0}\ =\ \wedge _{{{K}^{+}}}^{0}+\wedge _{C{{l}^{-}}}^{0}\]                         .....(3)                    By equation (1)+(2) ? (3)                    \[\because \]\[\wedge _{NaBr}^{0}\ =\ \wedge _{N{{a}^{+}}}^{0}+\wedge _{B{{r}^{-}}}^{0}\]                 \[=126+152-150=128\,\,Sc{{m}^{2}}\,mo{{l}^{-1}}\]


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