JEE Main & Advanced Chemistry Coordination Chemistry Question Bank Critical Thinking Coordination

  • question_answer
    An aqueous solution  of \[CoC{{l}_{2}}\] on addition of excess of concentrated HCl turns blue due to formation of [AIIMS 2005]

    A) \[[Co{{({{H}_{2}}O)}_{4}}C{{l}_{2}}]\]

    B) \[{{[Co({{H}_{2}}O)2C{{l}_{4}}]}^{2-}}\]

    C) \[{{[CoC{{l}_{4}}]}^{2-}}\]

    D) \[[Co({{H}_{2}}O)2C{{l}_{2}}]\]

    Correct Answer: C

    Solution :

    CoCl2 is a weak Lewis acid, reacting with chloride ion to produce salt containing the tetrahedral [CoCl4]2- ion. CoCl2 is blue when anhydrous, and a deep magneta colour when hydrated, for this reason it is widely used as an indicator for water.


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