JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Abnormal molecular mass

  • question_answer
    If \[\alpha \] is the degree of dissociation of \[N{{a}_{2}}S{{O}_{4}}\], the Vant Hoff's factor (i) used for calculating the molecular mass is [AIEEE 2005]

    A) \[1+\alpha \]         

    B) \[1-\alpha \]

    C) \[1+2\alpha \]       

    D) \[1-2\alpha \]

    Correct Answer: C

    Solution :

    \[N{{a}_{2}}S{{O}_{4}}\]      ? \[\] \[2N{{a}^{+}}\,\,\,\,\,+\,\,\,\,\,\,\,SO_{4}^{2-}\]             Mol. before diss. 1                      0                 0             Mol. after diss \[1-\alpha \]       \[2\alpha \]             \[1\alpha \]                 \[i=\frac{\text{Exp}\text{.C}\text{.P}\text{.}}{\text{Normal}\,\text{C}\text{.P}\text{.}}=1-\alpha +2\alpha +\alpha =1+2\alpha \]


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