JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank 2nd and 3rd law of thermodynamics and Entropy

  • question_answer
    \[\underset{{{S}^{o}}(298\,K)\,{{K}^{-1}}mo{{l}^{-1}}}{\mathop{{{H}^{+}}(aq)}}\,+\underset{-10.7}{\mathop{O{{H}^{-}}(aq)}}\,\xrightarrow{{}}\underset{+70}{\mathop{{{H}_{2}}O(l)}}\,\]                 Standard entropy change for the above reaction is  [DPMT 2004]

    A)                 \[60.3\,J{{K}^{-1}}mo{{l}^{-1}}\]               

    B)                 \[80.7\,J{{K}^{-1}}mo{{l}^{-1}}\]

    C)                 \[-70\,J{{K}^{-1}}mo{{l}^{-1}}\] 

    D)                 \[+10.7\,J{{K}^{-1}}mo{{l}^{-1}}\]

    Correct Answer: B

    Solution :

               \[\underset{{{S}^{o}}(298K){{K}^{-}}mo{{l}^{-1}}}{\mathop{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{{H}^{+}}_{(aq)}}}\,+\underset{-10.7}{\mathop{O{{H}^{-}}_{(aq)}}}\,\to \underset{+70}{\mathop{{{H}_{2}}{{O}_{(l)}}}}\,\]                    \[\Delta {{S}^{o}}(298K)=\Delta {{S}_{P}}-\Delta {{S}_{R}}\]\[=70-(-10.7+0)\]                                 \[80.7\,J{{K}^{-1}}\,mo{{l}^{-1}}\]


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