Answer:
Due to the strong
electron-withdrawing nature of \[-N{{O}_{2}}\] groups, both 2, 4-dinitrophenol
and 2, 4, 6-trinitrophenol are more acidic than carbonic acid and hence
dissolve in aq. \[N{{a}_{2}}C{{O}_{3}}\] solution to form the corresponding
sodium salts with the evolution of \[C{{O}_{2}}\].
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