12th Class Chemistry Haloalkanes and Haloarenes / हैलोएल्केन तथा हैलोएरीन्स

  • question_answer 88)
      Compound 'A' with molecular formula  is treated with aq. KOH solution. The rate of this reaction depends upon the concentration of the compound 'A' only. When another optically active isomer 'B' of this compound was treated with aq. KOH solution, the rate of reaction was found to be dependent on concentration of compound and KOH both. (i) Write down the structural formula of both compounds 'A' and 'B'. (ii) Out of these two compounds, which one will be converted to the product with inverted configuration.

    Answer:

                      Compound with MF is toluene. Since CH3 group is o, p-directing, therefore, chlorination of toluene with  in presence of  gives a mixture of o-chlorotoluene and p-chlorotoluene, in which the p- isomer predominates


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