12th Class Chemistry Electrochemistry / विद्युत् रसायन

  • question_answer 18)
    Depict the galvanic cell in which the reaction Zn (s) + 2Ag+ (aq)  Zn2+ (aq) + 2Ag(s) takes place. Further tell (i) Which of the electrode is negatively charged. (ii) The carriers of the current in the cell (iii) Individual reaction at each electrode.

    Answer:

    The cell is depicted as: Zn | Zn2+ (aq) || Ag+ (aq)| Ag (i) Zinc electrode is negatively charged electrode.             The electrons thus released move through the metal to reach another spot where H+ ions and the dissolved oxygen take up these electrons and reduction reaction takes place. Hence, this spot acts as the cathode: O2(g) + 4H+ (aq) + 4e? 2H­2O(l) The overall reaction is: Thus, an electrochemical cell is set up on the surface. Ferrous ions are further oxidized by the atmospheric oxygen to ferric ions which combine with water molecules to form hydrated ferric oxide, Fe2O3.xH2O, which is rust. (ii) The ions formed i.e., Zn2+ and Ag+ in the solution are the carriers of the current with in the cell. (iii) At anode:   At cathode:    


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