Solved papers for VIT Engineering VIT Engineering Solved Paper-2014

done VIT Engineering Solved Paper-2014 Total Questions - 120

  • question_answer1) A coil of resistance 10\[\Omega \] and an inductance 5 H is connected to a 100 V battery. The energy stored in the coil is

    A)
    325 erg                 

    B)
    125 J

    C)
    250 erg                 

    D)
    250 J

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  • question_answer2) A galvanometer has current range of 15 mA and voltage range 750 mV. To convert this galvanometer into an ammeter of range 25 A, the required shunt is

    A)
    0.8 \[\Omega \]               

    B)
    0.93\[\Omega \]

    C)
    0.03 \[\Omega \]            

    D)
    2.0 \[\Omega \]

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  • question_answer3) The daniel cell is balanced on 125 cm length of a potentiometer. Now, the cell is ?short circuited by a resistance of 2\[\Omega \], and the balance is obtained at 100 cm. The internal resistance of the daniel cell is

    A)
    \[\frac{4}{3}\Omega \]                 

    B)
    1.50 \[\Omega \]

    C)
    1.25\[\Omega \]                              

    D)
    0.5 \[\Omega \]

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  • question_answer4) Four resistances of 10\[\Omega \], 60\[\Omega \]., 100\[\Omega \]. and 200\[\Omega \]. respectively taken in order are used to form a Wheatstone's bridge. A 15V battery is connected to the ends of a 200\[\Omega \], resistance, the current through it will be

    A)
    \[7.5\times {{10}^{-5}}A\]           

    B)
    \[7.5\times {{10}^{-4}}A\]

    C)
    \[7.5\times {{10}^{-3}}A\]           

    D)
    \[7.5\times {{10}^{-2}}A\]

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  • question_answer5) circuit has a self-inductance of 1 H and carries a current of 2A. To prevent sparking, when the circuit is switched off, a capacitor which can withstand 400 V is used. The least capacitance of capacitor connected across the switch must be equal to

    A)
    50 \[\mu F\]                      

    B)
    25 \[\mu F\]

    C)
    100\[\mu F\]                     

    D)
    12.5 \[\mu F\]

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  • question_answer6) The output Y of the logic circuit shown in figure is best represented as

    A)
    \[\overset{-}{\mathop{A}}\,++\overline{B.C}\]                

    B)
     \[A+\overline{B}.C\]

    C)
    \[\overline{A+B.C}\]                     

    D)
     \[\overline{A+\overset{-}{\mathop{B}}\,.C}\]

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  • question_answer7) A resistor of 6 \[k\Omega \] with tolerance 10% and another resistance of 4 \[k\Omega \] with tolerance 10% are connected in series. The tolerance of the combination is about

    A)
    5%                                         

    B)
    10%

    C)
    12%                                       

    D)
    15% In series combination,                         \[=5000kW\]                          \[=\frac{mgh}{t}\] Error in combination               \[=7.5\times 9.8\times 4.7\]                \[=3454.5kW\]                \[\text{=}\frac{\text{Power used}}{\text{Power consumed}}\text{ }\!\!\times\!\!\text{ 100}\]               \[=\frac{3454.5}{5000}\times 100=69%\]                    = 10

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  • question_answer8) If we add impurity to a metal those atoms also deflect electrons. Therefore,

    A)
    the electrical and thermal conductivities both increase

    B)
    the electrical and thermal conductivities both decrease

    C)
    the electrical conductivity increases but thermal conductivity decreases

    D)
    the electrical conductivity decrease but thermal conductivity increases

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  • question_answer9) A proton and an a-particle, accelerated through the same potential difference, enter a region of uniform magnetic field normally. If the radius of the proton orbit is 10 cm, then radius of a-particle is

    A)
    10 cm                   

    B)
    \[10\sqrt{2}cm\]

    C)
    20 cm                   

    D)
    \[5\sqrt{2}cm\]

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  • question_answer10) An ammeter and a voltmeter of resistance R are connected in series to an electric cell of negligible internal resistance. Their reading are A and V respectively. If another resistance R is connected in parallel with the voltmeter, Then

    A)
    both/A and V will increase

    B)
    both A and V will decrease

    C)
     A will decrease and V will increase

    D)
    A will increase and V will decrease

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  • question_answer11) A neutron is moving with velocity u. It collides head on and elastically with an atom of mass number A. If the initial kinetic energy of the neutron is E , then how much kinetic energy will be retained by the neutron after reflection?

    A)
    \[{{\left( \frac{A}{A+1} \right)}^{2}}E\]                 

    B)
     \[\frac{A}{{{\left( A+1 \right)}^{2}}}E\]

    C)
     \[{{\left( \frac{A-1}{A+1} \right)}^{2}}E\]                            

    D)
    \[\frac{\left( A-1 \right)}{{{\left( A+1 \right)}^{2}}}E\]

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  • question_answer12) If a magnet is suspended at angle 30° to the magnet meridian, the dip of needle makes angle of 45° with the horizontal, the real dip is

    A)
    \[{{\tan }^{-1}}\left( \frac{\sqrt{3}}{2} \right)\]                 

    B)
    \[{{\tan }^{-1}}\left( \sqrt{3} \right)\]

    C)
    \[{{\tan }^{-1}}\left( \sqrt{\frac{3}{2}} \right)\]                 

    D)
     \[{{\tan }^{-1}}\left( \frac{2}{\sqrt{3}} \right)\]

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  • question_answer13) Which has more luminous efficiency ?

    A)
    A 40 W bulb

    B)
    A 40 W fluorescent tube

    C)
    Both have same

    D)
    Cannot say

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  • question_answer14) The resistance of a germanium junction diode whose V- I is shown in figure is\[\left( {{V}_{k}}=0.3V \right).\]

    A)
     5 \[k\Omega \]

    B)
     0.2 \[k\Omega \]

    C)
    2.3 \[k\Omega \]                             

    D)
    \[\left( \frac{10}{2.3} \right)k\Omega \]

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  • question_answer15) In hydrogen discharge tube, it is observed that through a given, cross-section \[3.31\times {{10}^{15}}\] electrons are moving from right to left and \[3.12\times {{10}^{5}}\] protons are moving from left to right. The current in the discharge tube and its direction will be

    A)
    2 mA, towards left

    B)
    2 mA, towards right

    C)
    1 mA, towards right

    D)
    2 mA, towards left

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  • question_answer16) In a semiconductor, separation between conduction and valence band is of the order of

    A)
    0 eV                                      

    B)
    1 eV

    C)
    10 eV                                    

    D)
    50 eV

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  • question_answer17) If 1000 droplets each of potential IV and radius r are mixed to form a big drop. Then, the potential of the drop as compared to small droplets, will be

    A)
    1000V                   

    B)
    800V

    C)
    100V   

    D)
    (d) 20V

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  • question_answer18) A Zener diode, having breakdown voltage equal to 15 V is used in a voltage regulator circuit shown in figure. The current through the diode is

    A)
    10mA

    B)
    15mA

    C)
    20 mA                  

    D)
    5 mA

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  • question_answer19) The activity of a radioactive sample is measured as \[{{N}_{0}}\]counts per minute at t = 0 and \[{{N}_{0}}/C\] counts per minute at t= 5 min. The time, (in minute) at which the activity reduces to half its value, is

    A)
    \[{{\log }_{e}}\frac{2}{5}\]                          

    B)
    \[\frac{5}{{{\log }_{e}}2}\]

    C)
    \[5{{\log }_{10}}2\]                         

    D)
    \[5{{\log }_{e}}2\]

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  • question_answer20) If the electron in the hydrogen atom jumps from third orbit to second orbit, the wavelength of the emitted radiation in term of Rydberg constant is

    A)
     \[\frac{6}{5R}\] 

    B)
                           \[\frac{36}{5R}\]

    C)
     \[\frac{64}{7R}\]                                             

    D)
     None of these

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  • question_answer21) Silver has a work function of 4.7 eV. When ultraviolet light of wavelength 100 nm is incident on it a potential of 7.7 V is required to stop the photoelectrons from reaching the collector plate. How much potential will be required to stop photoelectrons, when light of wavelength 200 nm is incident on it?

    A)
    15.4V 

    B)
    2.35V

    C)
    3.85V                    

    D)
    1.5V

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  • question_answer22) If the distance of 100 W lamp is increased from a photocell, the saturation current i in the photocell varies with the distance d as

    A)
    \[i\propto {{d}^{2}}\]                    

    B)
    \[i\propto d\]

    C)
    \[i\propto \frac{1}{d}\]                                

    D)
    \[i\propto \frac{1}{{{d}^{2}}}\]

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  • question_answer23) Following process is known as                 \[hv\leftrightarrow {{e}^{+}}+{{e}^{-}}\]

    A)
    pair production      

    B)
    photoelectric effect

    C)
     Compton effect      

    D)
      Zeeman effect

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  • question_answer24) During charging a capacitor, variations of potential V of the capacitor with time t is shown as

    A)
                                                                

    B)

    C)
                                                                      

    D)
              

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  • question_answer25) When a resistor of 11\[\Omega \] is connected in series with an electric cell. The current flowing in it is 0.5 A. Instead when a resistor of 5\[\Omega \] is connected to the same electric cell in series, the current increases by 0.4 A. The internal resistance of the cell is

    A)
    1.5\[\Omega \]                

    B)
    2\[\Omega \]

    C)
    2.5\[\Omega \] 

    D)
    3.5\[\Omega \]

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  • question_answer26) A battery is charged at a potential of 15 V in 8 h when the current flowing is 10A. The battery on discharge supplies a current of 5A for 15 h. The mean terminal voltage during discharge is 14V. The watt-hour efficiency of battery is

    A)
    80% 

    B)
                                           90%

    C)
    87.5%                                   

    D)
    82.5%  

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  • question_answer27)                A circular current carrying coil has a radius R. The distance from the centre of the coil on the axis, where the magnetic induction will be \[\frac{1}{8}\]th to its value at the centre of the coil is

    A)
    \[\frac{R}{\sqrt{3}}\]                     

    B)
    \[R\sqrt{3}\]

    C)
    \[2\sqrt{3}R\]                   

    D)
    \[\frac{2}{\sqrt{3}}R\]

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  • question_answer28) The incorrect statement regarding the lines of force of the magnetic field B is

    A)
    magnetic intensity is a measure of lines of force passing through unit area held normal to it

    B)
    magnetic lines of force from a close curve

    C)
    inside a magnet, its magnetic lines of force move from north pole of a magnetic towards its south pole

    D)
    due to a magnetic lines of force never cut each other

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  • question_answer29) Two coils have a mutual inductance 0.55 H. The current changes in the first coil according equation \[I={{I}_{0}}\]sin wt. where, \[{{I}_{0}}=10A\] and \[\omega =100\pi \]rad/s. The maximum value of emfin the second coil is

    A)
    \[2\pi \]                                               

    B)
    \[5\pi \]

    C)
     \[\pi \]                                

    D)
    \[4\pi \]

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  • question_answer30) An L-C-R circuit contains \[R=50\Omega ,\] L = 1 mH and \[C=0.\mu F.\]The impedance of the circuit will be minimum for a frequency of

    A)
    \[\frac{{{10}^{5}}}{2\pi }Hz\]   

    B)
    \[\frac{{{10}^{6}}}{2\pi }Hz\]

    C)
    \[2\pi \times {{10}^{5}}Hz\]        

    D)
    \[2\pi \times {{10}^{6}}Hz\]

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  • question_answer31) An eye can detect \[5\times {{10}^{4}}\]photons per square metre per sec of green light \[\left( \lambda =5000\overset{\circ }{\mathop{\text{A}}}\, \right)\]while the ear can detect \[{{10}^{-13}}W/{{m}^{2}}.\]. The factor by which the eye is more sensitive as a power detector then the ear is close to  

    A)
               5                                            

    B)
    10                   

    C)
    \[{{10}^{6}}\]                                    

    D)
    15   

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  • question_answer32)                  The amplification factor of a triode is 50. If the grid potential is decreased by 0.20 V. What increase, in plate potential will keep the plate current unchanged?

    A)
     5V                                         

    B)
    10V

    C)
    0.2 V                                     

    D)
     50 V          

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  • question_answer33)                                       If in a nuclear fission, piece of uranium of mass 5.0 g is lost, the energy obtained in kWh is

    A)
    \[1.25\times {{10}^{7}}\]             

    B)
    \[2.25\times {{10}^{7}}\]

    C)
    \[3.25\times {{10}^{7}}\]             

    D)
    \[0.25\times {{10}^{7}}\]

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  • question_answer34) Current in the circuit will be

    A)
     \[\frac{5}{40}A\]                            

    B)
    \[\frac{5}{50}A\]

    C)
     \[\frac{5}{10}A\]                            

    D)
     \[\frac{5}{20}A\]

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  • question_answer35) An installation consisting of an electric motor driving a water pump left 75 L of water per second to a height of 4.7 m. If the motor consumes a power of 5 kW, then the efficiency of the installation is

    A)
    39%                                       

    B)
    69%

    C)
    93%                                       

    D)
    96%

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  • question_answer36) The potential difference across the terminals of a battery is 50 V when 11 A current is drawn and 60 V, when 1 A current is drawn. The emf and the internal resistance of the battery are

    A)
    \[62V,2\Omega \]          

    B)
    \[63V,1\Omega \]

    C)
    \[61V,1\Omega \]   

    D)
    \[64V,2\Omega \]

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  • question_answer37) Beyond which frequency, the ionosphere bands any incident electromagnetic radiation but do not reflect it back towards the earth?

    A)
     50 MHz          

    B)
    40 MHz

    C)
    30 MHz          

    D)
    20 MHz

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  • question_answer38) A metallic surface ejects electrons. When exposed to green light of intensity I but no photoelectrons are emitted, when exposed to yellow light of intensity 7. It is possible to eject electron from the same surface by

    A)
    yellow light of same intensity which is more than

    B)
     green light of any intensity

    C)
    red light of any intensity

    D)
    None of the above

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  • question_answer39) An electron moves at right angle to a magnetic field of\[5\times {{10}^{-2}}\] T with a speed of \[6\times {{10}^{7}}\]m/s. If the specific charge of the electron is \[1.7\times {{10}^{11}}C/kg.\]The radius of the circular path will be

    A)
    2.9 cm                  

    B)
    3.9 cm

    C)
    2.35 cm  

    D)
    2 cm

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  • question_answer40) A solenoid 30 cm long is made by winding 2000 loops of wire on an iron rod whose cross-section is 1.5 cm2. If the relative permeability of the iron is 6000. What is the self-inductance of the solenoid?

    A)
    1.5H      

    B)
    2.5H

    C)
    3.5H                                      

    D)
    0.5H

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  • question_answer41) The standard molar heat of formation of ethane, \[\text{C}{{\text{O}}_{\text{2}}}\]and water (l) are respectively -21.1, -94.1 and - 68.3 kcal. The standard molar heat of combustion of ethane will be

    A)
    -372 kcal              

    B)
    162 kcal

    C)
    -240 kcal                              

    D)
    183.5 kcal

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  • question_answer42) The solubility product of \[\text{A}{{\text{g}}_{\text{2}}}\text{Cr}{{\text{O}}_{\text{4}}}\]is \[32\times {{10}^{-12}}.\] What is the concentration of \[\text{CrO}_{\text{4}}^{\text{-}}\] ions in that solution?

    A)
    \[\text{2 }\!\!\times\!\!\text{ 1}{{\text{0}}^{\text{-4}}}\text{M}\]

    B)
    \[\text{16 }\!\!\times\!\!\text{ 1}{{\text{0}}^{\text{-4}}}\text{M}\]

    C)
    \[\text{8 }\!\!\times\!\!\text{ 1}{{\text{0}}^{\text{-4}}}\text{M}\]         

    D)
    \[\text{8 }\!\!\times\!\!\text{ 1}{{\text{0}}^{\text{-8}}}\text{M}\]

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  • question_answer43) The equivalent conductivity of a solution containing 2.54 g of \[CuS{{O}_{4}}\] per L is \[91.0{{W}^{-1}}\]\[c{{m}^{2}}e{{q}^{-1}}.\] Its conductivity would be

    A)
    \[2.9\times {{10}^{-3}}{{\Omega }^{-1}}c{{m}^{-1}}\]

    B)
    \[1.8\times {{10}^{-2}}{{\Omega }^{-1}}c{{m}^{-1}}\]

    C)
    \[2.4\times {{10}^{-4}}{{\Omega }^{-1}}c{{m}^{-1}}\]

    D)
    \[3.6\times {{10}^{-3}}{{\Omega }^{-1}}c{{m}^{-1}}\]

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  • question_answer44) The half-life of two samples are 0.1 and 08 s. Their respective concentration are 400 and 50 respectively. The order of the reaction is

    A)
    0                                             

    B)
    2

    C)
    1                                             

    D)
    4

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  • question_answer45) Which sequence of reactions shows correct chemical relation between sodium and its compounds ?

    A)
    \[Na+{{O}_{2}}\to Na{{O}_{2}}\xrightarrow{HCl\left( aq \right)}\]                        \[NaCl\xrightarrow{C{{O}_{2}}}N{{a}_{2}}C{{O}_{3}}\xrightarrow{\Delta }Na\]

    B)
    \[Na\xrightarrow{{{O}_{2}}}N{{a}_{2}}O\xrightarrow{{{H}_{2}}O}NaOH\xrightarrow{C{{O}_{2}}}\]                                      \[N{{a}_{2}}C{{O}_{3}}\xrightarrow{\Delta }Na\]

    C)
    \[Na+{{H}_{2}}O\to NaOH\xrightarrow{HCl}NaCl\xrightarrow{C{{O}_{2}}}\]                                      \[N{{a}_{2}}C{{O}_{3}}\xrightarrow{\Delta }Na\]?

    D)
    \[Na+{{H}_{2}}O\to NaOH\xrightarrow{C{{O}_{2}}}N{{a}_{2}}C{{O}_{3}}\]                                      \[\xrightarrow{HCl}\underset{\left( molten \right)}{\mathop{NaCl}}\,\xrightarrow{Electrolysis}Na\]

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  • question_answer46) Purest form of iron is

    A)
    pig iron                

    B)
     wrought iron

    C)
    cast iron              

    D)
    steel

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  • question_answer47) Which has the smallest size?

    A)
    \[N{{a}^{+}}\]                                   

    B)
    \[M{{g}^{2+}}\]

    C)
    \[A{{l}^{3+}}\]                                  

    D)
    \[{{\text{P}}^{\text{5+}}}\]

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  • question_answer48) In the reaction, \[8Al+3F{{e}_{3}}{{O}_{4}}\to 4A{{l}_{2}}{{O}_{3}}+9Fe\] the number of electrons transferred from the reluctant to the bxidant is

    A)
    8                                             

    B)
     4

    C)
    16                                          

    D)
    24

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  • question_answer49) The bond angles of \[\text{N}{{\text{H}}_{\text{3}}}\text{,NH}_{\text{4}}^{\text{+}}\] and \[\text{NH}_{\text{2}}^{\text{-}}\] are in the order

    A)
     \[NH_{2}^{-}>N{{H}_{3}}>NH_{4}^{+}\]

    B)
    \[NH_{4}^{+}>N{{H}_{3}}>NH_{2}^{-}\]

    C)
    \[N{{H}_{3}}>NH_{2}^{-}>NH_{4}^{+}\]

    D)
    \[NH>NH_{4}^{+}>NH_{2}^{-}\]

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  • question_answer50) A gaseous mixture containing He, \[C{{H}_{4}}\]and \[S{{O}_{2}}\] was allowed to effuse through a fine hole then find what molar ratio of gases coming out initially? (Given mixture contains He, \[C{{H}_{4}}\]and  \[S{{O}_{2}}\] in 1 : 2 : 3 mole ratio).

    A)
     \[\sqrt{2}:\sqrt{2} & :3\]             

    B)
    2 : 2 : 3

    C)
     4 : 4 : 3     

    D)
    1:1:3

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  • question_answer51) According to Bohr's theory, the angular momentum for an electron of 3rd orbit is

    A)
    3 h               

    B)
    1.5 h

    C)
     9 h               

    D)
    \[2\frac{h}{\pi }\]

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  • question_answer52) 2.76 g of silver carbonate on being strongly heated yields a residue weighing

    A)
    3.54g                    

    B)
    3.0g  

    C)
    1.36g                    

    D)
    2.16g

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  • question_answer53) The final product (IV) in the sequence of reactions \[\begin{align}   & C{{H}_{3}}CHOH\xrightarrow{PB{{r}_{3}}}I\xrightarrow[Ether]{Mg} \\  & | \\  & C{{H}_{3}} \\ \end{align}\]                              ..

    A)
              \[\begin{align}   & C{{H}_{3}}-CHOC{{H}_{2}}C{{H}_{2}}OH \\  & | \\  & C{{H}_{3}} \\ \end{align}\]

    B)
                \[\begin{align}   & C{{H}_{3}}-CHC{{H}_{2}}C{{H}_{2}}Br \\  & | \\  & C{{H}_{3}} \\ \end{align}\]

    C)
                 \[\begin{align}   & C{{H}_{3}}-CH-C{{H}_{2}}C{{H}_{2}}OH \\  & | \\  & C{{H}_{3}} \\ \end{align}\]

    D)
                  \[\begin{align}   & C{{H}_{3}}-CHOC{{H}_{2}}C{{H}_{3}} \\  & | \\  & C{{H}_{3}} \\ \end{align}\]

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  • question_answer54) \[Ph-C\equiv C-C{{H}_{3}}\xrightarrow{H{{g}^{2+}}/{{H}^{+}}}A,\]

    A)
                                               

    B)

    C)
                                                                                  

    D)

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  • question_answer55) Which of the following has an ester linkage?

    A)
    Nylon-66             

    B)
    Dacron

    C)
    PVC                                       

    D)
    Bakelite

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  • question_answer56) Which of the following pairs give positive Tollen's test?

    A)
    Glucose, sucrose

    B)
    Glucose, fructose

    C)
    Hexanal, acetophenone

    D)
    Fructose, sucrose

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  • question_answer57) Peptisation involves

    A)
    precipitation of colloidal particles

    B)
    disintegration of colloidal aggregates

    C)
     evaporation of dispersion medium

    D)
    impact of molecules of the dispersion medium on the colloidal particles

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  • question_answer58) Which of the following has the maximum number of unpaired d-electrons?

    A)
    \[F{{e}^{2+}}\]                 

    B)
    \[C{{u}^{+}}\]

    C)
     Zn                                         

    D)
    \[N{{i}^{3+}}\]

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  • question_answer59) Iodine is formed when potassium iodide reacts with a solution of

    A)
    \[ZnS{{O}_{4}}\]                              

    B)
    \[CuS{{O}_{4}}\]

    C)
    \[{{\left( N{{H}_{4}} \right)}_{2}}S{{O}_{4}}\]                     

    D)
    \[N{{a}_{2}}S{{O}_{4}}\]

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  • question_answer60) Which of the following does not represent the correct order of the property indicated?

    A)
    \[S{{c}^{3+}}>C{{r}^{3+}}>F{{e}^{3+}}>M{{n}^{3+}}\] ? ionic radii

    B)
    \[Sc<Ti<Cr<Mn\] ? density

    C)
    \[M{{n}^{2+}}>N{{i}^{2+}}>C{{o}^{2+}}<F{{e}^{2+}}\] ? ionic radii

    D)
    \[FeO<CaO<MnO<CuO\] ? basic nature

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  • question_answer61) If the elevation in boiling point of a solution of 10 g of solute (mol. wt. = 100) in 100 g of water is \[\Delta {{T}_{b}},\]the ebullioscopic constant of water is

    A)
    10                                          

    B)
    100 \[{{T}_{b}}\]

    C)
    \[\Delta {{T}_{b}},\]                       

    D)
    \[\frac{\Delta {{T}_{b}}}{10}\]

    View Answer play_arrow
  • question_answer62) Which of the following compounds cannot be prepared singly by the Wurtz reaction?

    A)
    \[{{C}_{2}}{{H}_{6}}\]

    B)
    \[{{\left( C{{H}_{3}} \right)}_{2}}CHC{{H}_{3}}\]

    C)
    \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}\]

    D)
    All of the above can be prepared

    View Answer play_arrow
  • question_answer63) Which of the following oxides is strongly  asic?

    A)
    \[T{{l}_{2}}O\]                  

    B)
    \[{{B}_{2}}{{O}_{3}}\]

    C)
    \[A{{l}_{2}}{{O}_{3}}\]                  

    D)
    \[G{{a}_{2}}{{O}_{3}}\]

    View Answer play_arrow
  • question_answer64) In Langmuir's model of adsorption of a gas on a solid surface,

    A)
    the rate of dissociation of adsorbed molecules from the surface does not depend on the surface covered

    B)
    the adsorption at a single site on the surface may involve multiple molecules at the same time

    C)
    the mass of gas striking a given area of surface is proportional to the pressure of the gas

    D)
    the mass of gas striking a given area of surface is independent of the pressure of the gas

    View Answer play_arrow
  • question_answer65) How many sigma and pi-bonds are there in the. molecule        of        dicyanoethene (CN?CH\[\equiv \]CH?CN)?

    A)
    3 sigma and 3 pi

    B)
    5 sigma and 2 pi

    C)
    7 sigma and 5 pi

    D)
    2 sigma and 3 pi

    View Answer play_arrow
  • question_answer66) What will be the order of reactivity of the following carbonyl compounds with Grignard's reagent?

    A)
                                                                                       I > II > III > IV                                     

    B)
    IV > III > II > I

    C)
     II > I > IV > III

    D)
    III > II > I > IV

    View Answer play_arrow
  • question_answer67)   The final product ?C?  in the above reaction is

    A)
                                                                                    

    B)

    C)
                                                                           

    D)
                         

    View Answer play_arrow
  • question_answer68) Which of the following isomerism is shown by ethyl acetoacetate?

    A)
    Geometrical isomerism

    B)
    Keto-enol tautomerism

    C)
    Enantiomerism

    D)
    Diastereoisomerism

    View Answer play_arrow
  • question_answer69) The final product obtained in the reaction,

    A)
                                                                      

    B)
                  

    C)
                                                                     

    D)
                                            

    View Answer play_arrow
  • question_answer70) Among the following the strongest nucleophile is

    A)
    \[{{C}_{2}}{{H}_{5}}SH\]

    B)
    \[C{{H}_{3}}CO{{O}^{-}}\]

    C)
    \[C{{H}_{3}}N{{H}_{2}}\]

    D)
    \[NCCH_{2}^{-}\]

    View Answer play_arrow
  • question_answer71) Which set has different class of compounds?

    A)
    Tranquillizers-Equanil, heroin, valium

    B)
    Antiseptics-Bithional, dettol, boric acid

    C)
    Analgesics-Naproxen, morphine, aspirin

    D)
    Bactericidal-Penicillin, aminoglycosides, of loxacin

    View Answer play_arrow
  • question_answer72) The sodium extract, of an organic compound on acidification with acetic acid and addition of lead acetate solution gives a black precipitate. The organic compound contains

    A)
    nitrogen                              

    B)
    halogen

    C)
    sulphur                

    D)
    phosphorus

    View Answer play_arrow
  • question_answer73) The volume strength of 1.5 N \[{{H}_{2}}{{O}_{2}}\]solution is

    A)
    16.8L                     

    B)
     8.4 L

    C)
    4.2 L                      

    D)
     5.2 L

    View Answer play_arrow
  • question_answer74) \[MnO_{4}^{-}+8{{H}^{+}}+5{{e}^{-}}\to M{{n}^{2+}}+4{{H}_{2}}O;\]                                                \[{{E}^{\circ }}=1.51V\] \[Mn{{O}_{2}}+4{{H}^{+}}+2{{e}^{-}}\to M{{n}^{2+}}+2{{H}_{2}}O'\]                         \[{{E}^{\circ }}=1.23V{{E}^{\circ }}_{MnO_{4}^{-}|Mn{{O}_{2}}}is\]

    A)
     1.70 V                  

    B)
     0.91 V

    C)
     1.37 V                  

    D)
    0.548 V

    View Answer play_arrow
  • question_answer75) A metal has bcc structure and the edge length of its unit cell is 3.04\[\overset{\circ }{\mathop{\text{A}}}\,\]. The volume of the unit cell in cm 3 will be

    A)
    \[1.6\times {{10}^{21}}c{{m}^{3}}\]     

    B)
    \[2.81\times {{10}^{-23}}c{{m}^{3}}\]

    C)
    \[6.02\times {{10}^{-23}}c{{m}^{3}}\]  

    D)
    \[6.6\times {{10}^{-24}}c{{m}^{3}}\]

    View Answer play_arrow
  • question_answer76) Among \[{{\left[ Fe{{\left( {{H}_{2}}O \right)}_{6}} \right]}^{3+}},\]\[{{\left[ Fe{{\left( CN \right)}_{6}} \right]}^{3-}},\] \[{{\left[ Fe{{\left( Cl \right)}_{6}} \right]}^{3-}}\]species, the hybridisation state of the Fe atom are, respectively.

    A)
     \[{{d}^{2}}s{{p}^{3}},{{d}^{2}}s{{p}^{3}},s{{p}^{2}}{{d}^{2}}\]

    B)
    \[s{{p}^{3}}{{d}^{2}},{{d}^{2}}s{{p}^{3}},{{d}^{2}}s{{p}^{3}}\]

    C)
    \[s{{p}^{3}}{{d}^{2}},{{d}^{2}}s{{p}^{3}},s{{p}^{3}}{{d}^{2}}\]

    D)
     None of the above

    View Answer play_arrow
  • question_answer77) Which of the following hydrogen bonds are strongest in vapour phase?

    A)
    HF.......... HF

    B)
    HF.......... HCI

    C)
    HCI.......... HCI

    D)
    HF.......... HI

    View Answer play_arrow
  • question_answer78) The rate constant for forward reaction and backward reaction of hydrolysis of ester are \[1.1\times {{10}^{-2}}\] and \[1.5\times {{10}^{-3}}\]per   minute respectively. Equilibrium constant for the reaction is      \[C{{H}_{3}}COO{{C}_{2}}{{H}_{5}}+{{H}_{2}}O\rightleftharpoons C{{H}_{3}}COOH+{{C}_{2}}{{H}_{5}}OH\]

    A)
    33.7                                       

    B)
    7.33

    C)
    5.33                                       

    D)
     33.3

    View Answer play_arrow
  • question_answer79) 19.85 mL of 0.1 N NaOH reacts with 20 mL of HCI solution for complete neutralisation. The molarity of HCI solution is

    A)
    9.9                                         

    B)
    0.99

    C)
     0.099                   

    D)
    0.0099

    View Answer play_arrow
  • question_answer80) An /-shell containing 6 unpaired electrons can Exchange

    A)
    6 electrons                         

    B)
    9 electrons

    C)
    12 electrons                      

    D)
    15 electrons

    View Answer play_arrow
  • question_answer81)                   If the vertices of a triangle are A (0, 4, 1). B (2,3, -1) AND C (4, 5, 0), then the orthocentre of \[\Delta ABC,\] is

    A)
    (4, 5, 0)                

    B)
    (2, 3, -1)

    C)
    (-2, 3, -1)                             

    D)
     (2, 0, 2)

    View Answer play_arrow
  • question_answer82) The equation of normal to the curve \[y={{\left( 1+x \right)}^{y}}+{{\sin }^{-1}}\left( {{\sin }^{2}}x \right)\] at x = 0 is

    A)
     x + y = 1

    B)
     x ? y = 1

    C)
     x + y = - 1                           

    D)
     x ? y = - 1

    View Answer play_arrow
  • question_answer83) The value of c from the Lagrange?s mean value theorem for which \[f\left( x \right)=\sqrt{25-{{x}^{2}}}\] in [1, 5], is

    A)
    5                                             

    B)
    1

    C)
    \[\sqrt{15}\]                                      

    D)
    None of these

    View Answer play_arrow
  • question_answer84) If \[\text{A=}\left[ _{\text{5}}^{\text{3}}_{\text{7}}^{\text{4}} \right],\] then A. (adj A) is equal to

    A)
    A                                            

    B)
    |A|

    C)
    A|. l                                      

    D)
     None of these

    View Answer play_arrow
  • question_answer85) If there is an error of k% in measuring the edge of a cube, then the per cent rear in estimating its volume is

    A)
    k                                             

    B)
    3k

    C)
    \[\frac{k}{3}\]                                   

    D)
    None of these

    View Answer play_arrow
  • question_answer86) If the system of equation x + ky ? z = 0, 3x ? ky ? z = 0 and x ? 3y + z = 0, has non-zero solution, then k is equal to

    A)
    -1                                           

    B)
    0

    C)
    1             

    D)
    2

    View Answer play_arrow
  • question_answer87) If the points (1, 2, 3) and (2, -1, 0) lie on the opposite sides of the plane 2x + 3y ? 2z = k, then

    A)
    k < 1      

    B)
    k > 2

    C)
     k < 1 or k > 2                     

    D)
    1 < k < 2

    View Answer play_arrow
  • question_answer88) If \[\text{ }\!\!\Delta\!\!\text{ }\left( \text{x} \right)\left| \begin{matrix}    \text{1} & \text{cosx} & \text{1-cosx}  \\    \text{1+sinx} & \text{cosx} & \text{1+sinx-cosx}  \\    \text{sinx} & \text{sinx} & \text{1}  \\ \end{matrix} \right|\], then \[\int_{0}^{\pi /4}{\Delta }\left( x \right)dx\] is equal to

    A)
    \[\frac{1}{4}\]                                   

    B)
    \[\frac{1}{2}\]

    C)
     0                                            

    D)
    \[-\frac{1}{4}\]

    View Answer play_arrow
  • question_answer89) Let f? (x), be differentiable \[\forall x.\] If f(1) = - 2 and \[f'\left( x \right)\ge 2\forall x\in \] [ 1, 6], then

    A)
    f(6) < 8                 

    B)
    \[f\left( 6 \right)\ge 8\]

    C)
    \[f\left( 6 \right)\ge 5\]                

    D)
    \[f\left( 6 \right)\le 5\]

    View Answer play_arrow
  • question_answer90) If  \[{{\text{ }\!\!\Delta\!\!\text{ }}_{\text{r}}}\text{=}\left| \begin{matrix}    \text{2r-1} & ^{\text{m}}{{\text{C}}_{\text{r}}} & \text{1}  \\    {{\text{m}}^{\text{2}}}\text{-1} & {{\text{2}}^{\text{m}}} & \text{m+1}  \\    \text{si}{{\text{n}}^{\text{2}}}\left( {{\text{m}}^{\text{2}}} \right) & \text{si}{{\text{n}}^{\text{2}}}\left( \text{m} \right) & \text{si}{{\text{n}}^{\text{2}}}\left( \text{m+1} \right)  \\ \end{matrix} \right|\text{,}\] then value of \[\sum\limits_{r=0}^{m}{{{\Delta }_{r}}}\] is

    A)
    1                                             

    B)
     0

    C)
     2                                            

    D)
    None of these

    View Answer play_arrow
  • question_answer91) Two  lines   \[\frac{x-1}{2}=\frac{y+1}{3}=\frac{z-1}{4}\] and   \[\frac{x-3}{1}=\frac{y-k}{2}=z\]  intersect at a point, if k is equal to

    A)
    \[\frac{2}{9}\]                                   

    B)
    \[\frac{1}{2}\]

    C)
     \[\frac{9}{2}\]  

    D)
    \[\frac{1}{6}\]   

    View Answer play_arrow
  • question_answer92) The minimum value of \[\frac{x}{\log x}\] is

    A)
    e            

    B)
    \[\frac{1}{e}\]

    C)
    \[{{e}^{2}}\]                                      

    D)
    \[{{e}^{3}}\]

    View Answer play_arrow
  • question_answer93) The triangle formed by the tangent to the curve \[f\left( x \right)={{x}^{2}}+bx-b\] at the point (1, 1) and the coordinate axes lies in the first quadrant. If its area is 2, then the value of b is

    A)
    -1                                           

    B)
    3

    C)
    -3           

    D)
    1

    View Answer play_arrow
  • question_answer94) The statement \[\left( p\Rightarrow q \right)\Leftrightarrow \left( \sim p\wedge q \right)\] is a

    A)
    tautology                            

    B)
    contradiction

    C)
     Neither (a) nor (b)         

    D)
    None of these

    View Answer play_arrow
  • question_answer95) If x + i \[y=\frac{3}{2+\cos \theta +i\sin \theta },\] then \[{{x}^{2}}+{{y}^{2}}\]is equal to

    A)
    3x ? 4                   

    B)
    4x ? 3

    C)
    4x + 3                   

    D)
    None of these  

    View Answer play_arrow
  • question_answer96) The negation of \[\left( \sim p\wedge q \right)\vee \left( p\wedge \sim q \right)\]is

    A)
    \[\left( p\vee \sim q \right)\vee \left( \sim p\vee q \right)\]

    B)
    \[\left( p\vee \sim q \right)\wedge \left( \sim p\vee q \right)\]

    C)
    \[\left( p\wedge \sim q \right)\wedge \left( \sim p\vee q \right)\]

    D)
    \[\left( p\wedge \sim q \right)\wedge \left( p\vee \sim q \right)\]

    View Answer play_arrow
  • question_answer97) The normals  at three points O,Q and  R of the parabola meet at (h, k). The centroid of the lies on

    A)
    x = 0                                      

    B)
    y = 0

    C)
     x = -a                   

    D)
    y = a

    View Answer play_arrow
  • question_answer98) The minimum area of the triangle formed by any tangent to the ellipse \[\frac{{{x}^{2}}}{{{a}^{2}}}+\frac{{{y}^{2}}}{{{b}^{2}}}=1\] with the coordinate axes is

    A)
    \[{{a}^{2}}+{{b}^{2}}\]                  

    B)
     \[\frac{{{\left( a+b \right)}^{2}}}{2}\]

    C)
    ab                                          

    D)
     \[\frac{{{\left( a-b \right)}^{2}}}{2}\]

    View Answer play_arrow
  • question_answer99) If the line lx + my ? n = 0  will be a normal to the hyperbola, then \[\frac{{{a}^{2}}}{{{l}^{2}}}-\frac{{{b}^{2}}}{{{m}^{2}}}=\frac{{{\left( {{a}^{2}}+{{b}^{2}} \right)}^{2}}}{k},\] where k is equal to

    A)
    n                                            

    B)
    \[{{n}^{2}}\]

    C)
    \[{{n}^{3}}\]                                      

    D)
    None of these

    View Answer play_arrow
  • question_answer100) If \[\cos \alpha +i\sin \alpha ,b=\cos \beta +i\sin \beta ,\]\[c=\cos \gamma +i\sin \gamma \] and \[\frac{b}{c}+\frac{c}{a}+\frac{a}{b}=1,\]then \[\cos \left( \beta -\gamma  \right)+\cos \left( \gamma -\alpha  \right)+\cos \left( \alpha -\beta  \right)\] is equal to

    A)
    \[\frac{3}{2}\]                                   

    B)
    \[-\frac{3}{2}\]

    C)
    0                                             

    D)
    1

    View Answer play_arrow
  • question_answer101) If  \[\left| z+4 \right|\le 3,\] then the greatest and the least value of |z + 1| are

    A)
    -1, 6                                      

    B)
    6, 0

    C)
    6, 3                                        

    D)
    None of these

    View Answer play_arrow
  • question_answer102) The angle between lines joining the origin to the point of intersection of the line \[\sqrt{3}x+y=2\] and the curve \[{{y}^{2}}-{{x}^{2}}=4\] is

    A)
    \[{{\tan }^{-1}}\frac{2}{\sqrt{3}}\]                           

    B)
    \[\pi /6\]

    C)
    \[{{\tan }^{-1}}\left( \frac{\sqrt{3}}{2} \right)\]                 

    D)
    \[\pi /2\]

    View Answer play_arrow
  • question_answer103) If the area of the triangle on the complex plane formed by the points z, z + iz and iz is 200, then the value of 3 |z| must be equal to

    A)
    20                                          

    B)
    40

    C)
     60                                         

    D)
    80

    View Answer play_arrow
  • question_answer104) Equation  of the chord of the hyperbola \[25{{x}^{2}}-16{{y}^{2}}=400\] which is bisected at the point (6, 2) is

    A)
    6x ? 7y = 418     

    B)
    75x ? 16y = 418

    C)
    25x ? 4y = 400   

    D)
    None of these

    View Answer play_arrow
  • question_answer105) If a plane meets the coordinate axes at A, B and C such that the centroid of the triangle is (1, 2, 4) then equation of the plane is

    A)
    x + 2y + 4z = 12 

    B)
    4x + 2y + z = 12

    C)
     x + 2y + 4z = 3  

    D)
    4x + 2y + z = 3

    View Answer play_arrow
  • question_answer106) The volume of the tetrahedron included between the plane  3x + 4y ? 5z ? 60 = 0 and the coordinate planes is

    A)
    60                                          

    B)
    600

    C)
    720                                        

    D)
    400

    View Answer play_arrow
  • question_answer107) \[\int_{0}^{2\pi }{\left( \sin x|\sin x| \right)}\]dx  is equal to

    A)
    0                                             

    B)
    4

    C)
    8                                             

    D)
    1

    View Answer play_arrow
  • question_answer108) The value of \[\int_{0}^{\sqrt{2}}{[{{x}^{2}}]dx,}\] where [.] is the greatest integer function is

    A)
    \[2-\sqrt{2}\]

    B)
    \[2+\sqrt{2}\]

    C)
    \[\sqrt{2}-1\]                    

    D)
    \[\sqrt{2}-2\]

    View Answer play_arrow
  • question_answer109) If l (m. n) = \[\int_{0}^{1}{{{t}^{m}}{{\left( 1+t \right)}^{n}}dt,}\] then the expression for l (m, n) in terms of l (m +  n + 1) is

    A)
    \[\frac{{{2}^{n}}}{m+1}-\frac{n}{m+1}.l\left( m+1,n+1 \right)\]

    B)
    \[\frac{n}{m+1}.l\left( m+1,n-1 \right)\]

    C)
    \[\frac{2n}{m+1}+\frac{n}{m+1}l.\left( m+1,n-1 \right)\]

    D)
    \[\frac{m}{n+1}.l\left( m+1,n-1 \right)\]

    View Answer play_arrow
  • question_answer110) The area in the first quadrant between \[{{x}^{2}}+{{y}^{2}}={{\pi }^{2}}\] and y = sin x is

    A)
    \[\frac{{{\pi }^{3}}-8}{4}\]

    B)
    \[\frac{{{\pi }^{3}}}{4}\]

    C)
    \[\frac{{{\pi }^{3}}-16}{4}\]                         

    D)
    \[\frac{{{\pi }^{3}}-8}{2}\]

    View Answer play_arrow
  • question_answer111) The area bounded by \[y=x{{e}^{|x|}}\] and lines |x| = 1, y = 0 is

    A)
    4 sq units                            

    B)
    6 sq units

    C)
    1 sq units                            

    D)
    2 sq units

    View Answer play_arrow
  • question_answer112) The solution of \[\frac{dy}{dx}=\frac{{{x}^{2}}+{{y}^{2}}+1}{2xy},\] satisfying y(1) = 0 is given by

    A)
    hyperbola          

    B)
    circle

    C)
    ellipse                  

    D)
    parabola

    View Answer play_arrow
  • question_answer113) If  \[x.\frac{dy}{dx}+y=x.\frac{f\left( xy \right)}{f'\left( xy \right)},\] then f(xy) is equal to

    A)
    \[k.{{e}^{\frac{{{x}^{2}}}{2}}}\]

    B)
    \[k.{{e}^{{{y}^{2}}/2}}\]

    C)
    \[k.{{e}^{{{x}^{2}}}}\]                   

    D)
    \[k.{{e}^{\frac{xy}{2}}}\]

    View Answer play_arrow
  • question_answer114) The differential equation of the rectangular hyperbola, where axes are the asymptotes of the  hyperbola, is

    A)
    \[y\frac{du}{dx}=x\]                      

    B)
    \[x\frac{du}{dx}=-y\]

    C)
    \[x\frac{dy}{dx}=y\]                      

    D)
    xdy + ydx = c

    View Answer play_arrow
  • question_answer115) The length of longer diagonal of the parallelogram constructed on 5a+2b and a -3b, if it is given that \[\left| a \right|=2\sqrt{2},\left| b \right|=3\]and the angle between a and b is \[\frac{\pi }{4},\] is

    A)
    15                                          

    B)
    \[\sqrt{113}\]

    C)
    \[\sqrt{593}\]   

    D)
    \[\sqrt{369}\]

    View Answer play_arrow
  • question_answer116) If \[r=\alpha b\times c+\beta c\times a+\gamma a\times b\]and [a b c] =2, then \[\alpha +\beta +\gamma \] is equal to

    A)
    \[r.[b\times c+c\times a+a\times b]\]

    B)
    \[\frac{1}{2}r.\left( a+b+c \right)\]

    C)
    2r. (a + b + c)

    D)
    4

    View Answer play_arrow
  • question_answer117) If a, b, c are three non-coplanar vectors and p, q, r are reciprocal vectors, then (isl + mb + nc)  (lp + mq + nr) is equal to

    A)
    l + m + n              

    B)
    \[{{l}^{3}}+{{m}^{3}}+{{n}^{3}}\]

    C)
    \[{{l}^{2}}+{{m}^{2}}+{{n}^{2}}\]              

    D)
    None of these

    View Answer play_arrow
  • question_answer118) If the integers m and n are chosen at random from 1 to 100, then the probability that a number of the form \[{{7}^{n}}+{{7}^{m}}\] is divisible by 5, equals to

    A)
    \[\frac{1}{4}\]           

    B)
    \[\frac{1}{2}\]

    C)
    \[\frac{1}{8}\]                                   

    D)
    \[\frac{1}{3}\]

    View Answer play_arrow
  • question_answer119) Let X denote the sum of the numbers  obtained when two fair dice are rolled. The variance and standard deviation of X are

    A)
    \[\frac{31}{6}and\sqrt{\frac{31}{6}}\]

    B)
    \[\frac{35}{6}and\sqrt{\frac{35}{6}}\]

    C)
    \[\frac{17}{6}and\sqrt{\frac{17}{6}}\]

    D)
    \[\frac{31}{6}and\sqrt{\frac{35}{6}}\]

    View Answer play_arrow
  • question_answer120) A four-digit number is formed by the digits 1, 2, 3, 4 with no repetition. The probability that the number is odd, is

    A)
    zero                      

    B)
    \[\frac{1}{3}\]

    C)
    \[\frac{1}{4}\]                  

    D)
     None of these

    View Answer play_arrow

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