VIT Engineering VIT Engineering Solved Paper-2009

  • question_answer
    Assertion [A] K, Rb and Cs form superoxides. Reason [R] The stability of the superoxides increases from K to Cs due to decrease in lattice energy. The correct answer is

    A)  Both [A] and [R] are true and [R] is the correct explanation of [A]

    B)  Both [A] and [R] are true but [R] is not the correct explanation of [A]

    C)  [A] is true but [R] is not true

    D)  [A] is not true but [R] is true

    Correct Answer: C

    Solution :

     Superoxides are the species having an \[O-O\] bond and O in an oxidation state of \[-\frac{1}{2}\] (superoxide ion is \[O_{2}^{-}\]). Usually these are formed by active metals such as \[K{{O}_{2}},Rb{{O}_{2}}\] and \[Cs{{O}_{2}}\]. For the salts of larger anions (like \[O_{2}^{-}\]), lattice energy increases in a group. Since, lattice energy is the driving force for the formation of an ionic compound and its stability, the stability of the superoxides from K to Cs also increases.


You need to login to perform this action.
You will be redirected in 3 sec spinner