Uttarakhand PMT Uttarakhand PMT Solved Paper-2011

  • question_answer
    Which of the following on heating does not form an anhydride?

    A)  Oxalic acid       

    B)  Succinic acid

    C)  Maleic acid       

    D)  Glutamic acid

    Correct Answer: A

    Solution :

     Since, three membered rings are quite unstable, hence oxalic acid on heating does not form an anhydride. It decomposes to give \[C{{O}_{2}},CO\] and\[{{H}_{2}}O\]. \[\underset{COOH}{\overset{COOH}{\mathop{|}}}\,\xrightarrow[{}]{\Delta }C{{O}_{2}}+\underset{\begin{smallmatrix}  \downarrow \Delta  \\  CO+{{H}_{2}}O \end{smallmatrix}}{\mathop{[HCOOH]}}\,\]


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