Uttarakhand PMT Uttarakhand PMT Solved Paper-2007

  • question_answer
    Aniline reacts with\[NaN{{O}_{2}}\]and\[HCl\]at room temperature to give

    A)  nitroaniline   

    B)  phenol

    C)  chloroaniline   

    D)  diazonium chloride

    Correct Answer: B

    Solution :

     At room temperature, initially formed diazonium chloride decomposes to give phenol. \[{{C}_{6}}{{H}_{5}}N{{H}_{2}}\xrightarrow[room\text{ }temp.]{NaN{{O}_{2}}/HCl}\underset{benzene\text{ }diazonium\text{ }chloride}{\mathop{[{{C}_{6}}{{H}_{5}}-{{N}^{+}}\equiv NC{{l}^{-}}]}}\,\]               \[\xrightarrow[-HCl,-{{N}_{2}}]{{{H}_{2}}O}\underset{phenol}{\mathop{{{C}_{6}}{{H}_{5}}OH}}\,\]


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