Uttarakhand PMT Uttarakhand PMT Solved Paper-2007

  • question_answer
    Which of the following substances has the highest melting point?

    A)  \[NaCl\]          

    B)  \[KCl\]

    C)  \[MgO\]          

    D)  \[BaO\]

    Correct Answer: C

    Solution :

     Melting points, among other things, depend upon lattice energy. Now\[NaCl\]and\[KCl\]have unit charge on their ions while\[MgO\]and\[BaO\] have two units of charge, therefore, lattice energies of\[MgO\]and\[BaO\]are expected to be larger than those of\[NaCl\]and\[KCl\]. Further since\[M{{g}^{2+}}\]is smaller than\[B{{a}^{2+}},\]therefore, \[MgO\]has the highest lattice energy and hence has the highest melting point.


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