Uttarakhand PMT Uttarakhand PMT Solved Paper-2006

  • question_answer
    Which carbocation is most stable?

    A)  \[C{{H}_{3}}\overset{+}{\mathop{C}}\,{{H}_{2}}\]       

    B)  \[\overset{+}{\mathop{C}}\,{{H}_{3}}\]

    C)  \[{{C}_{6}}{{H}_{5}}\overset{+}{\mathop{C}}\,{{H}_{2}}\]      

    D)  \[C{{H}_{3}}C{{H}_{2}}\overset{+}{\mathop{C}}\,{{H}_{2}}\]

    Correct Answer: C

    Solution :

     A phenyl group, in which there is a flow of electron due to resonance of the benzene ring, generally causes\[-I\]effect, but truely speaking it can act as both electron donating as well as electron withdrawing groups, depending upon the nature of group with which it is attached. In\[{{C}_{6}}{{H}_{5}}CH_{2}^{+},\]phenyl group is attached to electron deficient group, hence, it will donate electron due to resonance in benzene ring and thus stabilise the cation.


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