Answer:
(i) \[{{C}_{4}}{{H}_{8}}\] : Butene-alkene (unsaturated hydro-carbon) (ii) \[{{C}_{3}}{{H}_{8}}\] : propane-alkane (saturated hydrocarbon) \[{{C}_{4}}{{H}_{8}}\] i.e. butene shows addition reaction as it is unsaturated hydrocarbon \[H-\underset{\begin{smallmatrix} | \\ H \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-\underset{\begin{smallmatrix} | \\ H \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-\underset{{}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,=\underset{{}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-H+C{{l}_{2}}\xrightarrow{{}}H-\underset{\begin{smallmatrix} | \\ H \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-\underset{\begin{smallmatrix} | \\ H \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-\underset{\begin{smallmatrix} | \\ Cl \end{smallmatrix}}{\overset{\begin{smallmatrix} H \\ | \end{smallmatrix}}{\mathop{C}}}\,-H\]
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