RAJASTHAN PMT Rajasthan - PMT Solved Paper-2011

  • question_answer
    A is

    A)

    B)

    C)  \[1:1\] mixture of both (a) and (b)

    D) \[C{{H}_{3}}-CH=CH-C{{H}_{3}}\]

    Correct Answer: B

    Solution :

    The \[{{S}_{{{N}^{2}}}}\] reactions of alkyl halides are concerted reactions, \[i.e.,\] take place in one step. These occur through a transition state in which both the reactants are partially bonded to each other, the attack of the nucleophile (i.e., \[O{{H}^{-}}\] ion) occurs from the back side and the leaving group (i.e., \[B{{r}^{-}}\] ion) leaves from the front side. As a result, the \[{{S}_{{{N}^{2}}}}\] reactions of optically active alkyl halides are always accompanied by inversion of configuration at the asymmetric centre, which is also known as Walden inversion and the products are not enantiomers.


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