A) \[CH{{I}_{3}}\]and\[HCOOK\]
B) \[CH{{I}_{3}}\]and\[C{{H}_{3}}COOK\]
C) \[C{{H}_{4}}\]and\[HCOOK\]
D) \[CH{{I}_{3}}\]and\[{{H}_{2}}\]
Correct Answer: A
Solution :
\[{{C}_{2}}{{H}_{5}}OH+4{{I}_{2}}+6NaOH\xrightarrow{{}}\underset{Iodoform}{\mathop{CH{{I}_{3}}}}\,\] \[+HCOONa+5NaI+5{{H}_{2}}O\] \[CH{{I}_{3}}+3KOH\xrightarrow{{}}\left[ H-\underset{\begin{smallmatrix} | \\ OH \end{smallmatrix}}{\overset{\begin{smallmatrix} OH \\ | \end{smallmatrix}}{\mathop{C}}}\,-OH \right]\xrightarrow{{{H}_{2}}O}\] \[H-\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,-OH\] \[H-\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,-OH+KOH\xrightarrow{{}}H-\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,-OK+{{H}_{2}}O\]
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