A) \[{{C}_{6}}{{H}_{5}}NC\]
B) \[{{C}_{6}}{{H}_{5}}CN\]
C) \[{{C}_{6}}{{H}_{5}}Cl\]
D) \[{{C}_{6}}{{H}_{5}}NH{{C}_{6}}{{H}_{5}}\]
Correct Answer: A
Solution :
\[\underset{Aniline}{\mathop{{{C}_{6}}{{H}_{5}}N{{H}_{2}}}}\,+\underset{Chloroform}{\mathop{CHC{{l}_{3}}}}\,+3KOH\xrightarrow{{}}\] \[\underset{\begin{smallmatrix} Phenyl \\ isocyanide \\ (bad\ \,smell) \end{smallmatrix}}{\mathop{{{C}_{6}}{{H}_{5}}NC}}\,+3KCl+3{{H}_{2}}O\] Thus, phenyl isocyanide is formed.
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