RAJASTHAN PMT Rajasthan - PMT Solved Paper-2003

  • question_answer
    Glycerol at \[530K\]reacts with oxalic acid to produce

    A)  glyceraldehyde

    B)         allyl alcohol

    C)  formic acid    

    D)  acetic acid

    Correct Answer: B

    Solution :

    Glycerol at \[530\text{ }K\]reacts with oxalic acid to produce allyl alcohol. \[\underset{\text{Glycerol dioxalate}}{\mathop{\underset{\underset{C{{H}_{2}}OH}{\overset{CHOOC}{\mathop{|}}}\,}{\overset{C{{H}_{2}}OOC)}{\mathop{|}}}\,}}\,\xrightarrow[(-2\,\,C{{O}_{2}})]{}\underset{\text{Allyl Alcohol}}{\mathop{\underset{\underset{C{{H}_{2}}OH}{\overset{CH}{\mathop{|}}}\,}{\overset{C{{H}_{2}}}{\mathop{||}}}\,}}\,\]


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