RAJASTHAN PMT Rajasthan - PMT Solved Paper-1998

  • question_answer
    \[{{C}_{2}}{{H}_{5}}-O-{{C}_{2}}{{H}_{5}}\]on reaction with chlorine in the presence of light gives:

    A) \[C{{H}_{3}}COCl\]

    B)                         \[{{({{C}_{2}}C{{l}_{5}})}_{2}}O\]

    C)                         \[C{{H}_{3}}-Cl\]

    D)                         all of these

    Correct Answer: B

    Solution :

    \[{{C}_{2}}{{H}_{5}}-O-{{C}_{2}}{{H}_{5}}+10C{{l}_{2}}\xrightarrow{hv}\] \[\underset{Perchloro\,\,di\,ethyl\,\,ether}{\mathop{{{C}_{2}}C{{l}_{5}}-O-{{C}_{2}}C{{l}_{5}}+10HCl}}\,\]


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