RAJASTHAN PMT Rajasthan - PMT Solved Paper-1997

  • question_answer
    Methyl amine on reaction with \[HN{{O}_{2}}\] gives:

    A)  \[C{{H}_{2}}-O-C{{H}_{3}}\]

    B)                         \[C{{H}_{3}}-O-N=0\]

    C)                         both (a) and (b)

    D)                         none of these

    Correct Answer: C

    Solution :

    \[C{{H}_{3}}N{{H}_{2}}+2HN{{O}_{2}}\xrightarrow{{}}\] \[C{{H}_{3}}-\underset{Methyl\,nitrte}{\mathop{O-N=O}}\,+{{N}_{2}}+2{{H}_{2}}O\]                 \[2C{{H}_{3}}N{{H}_{2}}+2HN{{O}_{2}}\xrightarrow{{}}\]                                 \[\underset{Dimethyl\,\,ether}{\mathop{C{{H}_{3}}-O-C{{H}_{3}}}}\,+2{{N}_{2}}+3{{H}_{2}}O\]


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