RAJASTHAN PMT Rajasthan - PMT Solved Paper-1996

  • question_answer
    Which of the following compounds is formed by the reaction of propyne with \[{{H}_{2}}S{{O}_{4}}\] and mercuric ions?

    A)  Propanal      

    B)                         2-propanal

    C)                         Propanone     

    D)                         Propane diol

    Correct Answer: C

    Solution :

    \[C{{H}_{3}}-C\equiv CH+{{H}_{2}}O\xrightarrow[1%\,HgS{{O}_{2}}]{dil\,\,{{H}_{2}}S{{O}_{4}}}\] \[\underset{Unstable}{\mathop{\left\{ C{{H}_{3}}-\underset{O-H}{\mathop{\underset{|}{\mathop{C}}\,}}\,=C{{H}_{2}} \right\}}}\,\xrightarrow{tautomerism}\] \[\xrightarrow{\text{Propyne}}\underset{Acetone\,\,\text{(Propanone)}}{\mathop{C{{H}_{3}}-\underset{O}{\mathop{\underset{||}{\mathop{C}}\,}}\,-C{{H}_{3}}}}\,\]


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