RAJASTHAN ­ PET Rajasthan PET Solved Paper-2012

  • question_answer
    Acetylene does not react with

    A)  Na

    B)  \[HCl\]

    C)  ammoniacal \[AgN{{O}_{3}}\]

    D)  \[NaOH\]

    Correct Answer: D

    Solution :

     [a] \[CH\equiv CH+Na\xrightarrow[{}]{{}}CH\equiv {{C}^{-}}N{{a}^{+}}\frac{1}{2}{{H}_{2}}\] [b] \[CH\equiv CH+ammoniacal\text{ }AgN{{O}_{3}}\xrightarrow[{}]{{}}\]           \[CH\equiv {{C}^{-}}A{{g}^{+}}\] white ppt [c] \[CH\equiv CH+HCl\xrightarrow[{}]{{}}C{{H}_{2}}=CH-Cl\] (usually occurs in the presence of\[H{{g}^{2+}}\]) [d] \[CH\equiv CH+NaOH\xrightarrow[{}]{{}}\]no reaction (because of hard and soft acid and base (HSAB) theory).


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