RAJASTHAN ­ PET Rajasthan PET Solved Paper-2001

  • question_answer
    Which of the following will give silver mirror test?

    A)  Glucose                                   

    B)  Fructose

    C)  Starch           

    D)  Sucrose

    Correct Answer: A

    Solution :

     Aldehyde group\[(-CHO)\]reduces Tollen's reagent and gives silver mirror. Tollen's reagent is ammoniacal silver nitrate solution. Glucose contains\[-CHO\]group hence it gives silver mirror test. \[\underset{\begin{smallmatrix}  | \\  C{{H}_{2}}OH \end{smallmatrix}}{\overset{\begin{smallmatrix}  CHO \\  | \end{smallmatrix}}{\mathop{{{(CHOH)}_{4}}}}}\,+\underset{\begin{smallmatrix}  Tollen's \\  reagent \end{smallmatrix}}{\mathop{A{{g}_{2}}O}}\,\xrightarrow[{}]{{}}\underset{\begin{smallmatrix}  | \\  C{{H}_{2}}OH \end{smallmatrix}}{\overset{\begin{smallmatrix}  COOH \\  | \end{smallmatrix}}{\mathop{{{(CHOH)}_{4}}}}}\,+\underset{\begin{smallmatrix}  silver \\  mirror \end{smallmatrix}}{\mathop{2Ag\downarrow }}\,\]


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