Punjab Medical Punjab - MET Solved Paper-2003

  • question_answer
    What is obtained, when potassium succinate solution is electrolysed?

    A)  Ethane                                

    B)  Ethene

    C)  Ethyne                                

    D)  All of these

    Correct Answer: B

    Solution :

    This is an example of Kolbes electrolysis. Ethylene is obtained on electrolysis of potassium succinate. \[\begin{align}   & C{{H}_{2}}COOK \\  & | \\  & C{{H}_{2}}COOK \\ \end{align}\]      \[\xrightarrow{electrolysis}\]\[\begin{align}   & C{{H}_{2}}CO{{O}^{-}} \\  & | \\  & C{{H}_{2}}CO{{O}^{-}}+2{{K}^{+}} \\ \end{align}\] At anode         \[\begin{align}   & C{{H}_{2}}CO{{O}^{-}} \\  & | \\  & C{{H}_{2}}CO{{O}^{-}} \\ \end{align}\]\[\xrightarrow{-2{{e}^{-}}}\]\[\begin{align}   & C{{H}_{2}}CO{{O}^{\centerdot }} \\  & | \\  & C{{H}_{2}}CO{{O}^{\centerdot }} \\ \end{align}\]\[\xrightarrow{-2C{{O}_{2}}}\]\[\begin{align}   & CH_{2}^{\centerdot } \\  & | \\  & CH_{2}^{\centerdot } \\ \end{align}\]\[\xrightarrow{{}}\]\[\begin{align}   & C{{H}_{2}} \\  & || \\  & \underset{Ethene}{\mathop{C{{H}_{2}}}}\, \\ \end{align}\]


You need to login to perform this action.
You will be redirected in 3 sec spinner