MGIMS WARDHA MGIMS WARDHA Solved Paper-2015

  • question_answer
    Cone.\[{{H}_{2}}S{{O}_{4}}\]displaces hydrogen chloride from chlorides because

    A)  it is stronger acid

    B)  sulphates are less soluble than chlorides

    C)  sulphates are more soluble than chlorides

    D)  \[HCl\] is a gas while\[{{H}_{2}}S{{O}_{4}}\] is a liquid

    Correct Answer: D

    Solution :

                    Gas (\[HCl,\]more volatile) can be displaced more easily from the chloride salt solution by \[{{H}_{2}}S{{O}_{4}}\] which is less volatile. \[NaCl+\underset{\begin{smallmatrix}  less \\  volatile \end{smallmatrix}}{\mathop{{{H}_{2}}S{{O}_{4}}}}\,\xrightarrow[{}]{{}}NaHS{{O}_{4}}+\underset{\begin{smallmatrix}  more \\  volatile \end{smallmatrix}}{\mathop{HCl}}\,\]


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