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MGIMS WARDHA MGIMS WARDHA Solved Paper-2015

  • question_answer
    The total number of possible isomers of the complex compound\[|C{{u}^{II}}{{(N{{H}_{3}})}_{4}}||P{{t}^{II}}C{{l}_{4}}|\]is

    A)  3                                            

    B)  6     

    C)  5                                            

    D)  4

    Correct Answer: D

    Solution :

                    \[|C{{u}^{II}}(N{{H}_{3}})||P{{t}^{II}}C{{l}_{4}}|\]shows \[|Cu(N{{H}_{3}})Cl||PtC{{l}_{3}}N{{H}_{3}}|,\] \[|Cu(N{{H}_{3}})C{{l}_{3}}||Pt{{(NH)}_{3}}Cl|\]and\[|CuC{{l}_{4}}||Pt{{(N{{H}_{3}})}_{4}}|\].Other isomers such as\[|Cu{{(N{{H}_{3}})}_{2}}C{{l}_{2}}||Pt{{(N{{H}_{3}})}_{2}}C{{l}_{2}}|\] does not exist due to both parts being neutral.


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