A) action of nitrogen oxides on hydrocarbons in presence of sunlight
B) action of\[C{{O}_{2}}\]on hydrocarbons in presence of sunlight
C) action of hydrogen sulphide on hydrocarbon in presence of sunlight
D) None of the above
Correct Answer: A
Solution :
\[RCHO\xrightarrow[{}]{\overline{O}H}\underset{Acyl\text{ }radical\text{ }Peroxy,\text{ }acyl\text{ }radical}{\mathop{R-\underset{\begin{smallmatrix} || \\ O \end{smallmatrix}}{\mathop{{{C}^{\bullet }}}}\,\xrightarrow[{}]{{{O}_{2}}}\underset{\begin{smallmatrix} || \\ O \end{smallmatrix}}{\mathop{RCO{{O}^{\bullet }}}}\,}}\,\] \[\underset{PAN}{\overset{\downarrow N{{O}_{2}}}{\mathop{\underset{\begin{smallmatrix} || \\ O \end{smallmatrix}}{\mathop{R-COO{{N}_{2}}}}\,}}}\,\] \[{{C}_{6}}{{H}_{6}}CHO\xrightarrow[N{{O}_{2}}]{\overline{O}H/{{O}_{2}}}\underset{PBN}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix} |\,| \\ O \end{smallmatrix}}{\mathop{C}}\,-OON{{O}_{2}}}}\,\]
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