MGIMS WARDHA MGIMS WARDHA Solved Paper-2014

  • question_answer
    Corrosion   of  iron   is   essentially   an electrochemical phenomenon where the cell reactions are

    A)  Fe is oxidised to\[F{{e}^{2+}}\]and dissolved oxygen in water is reduced to\[O{{H}^{-}}\]

    B)  Fe is oxidised to\[F{{e}^{3+}}\]and\[{{H}_{2}}O\]is reduced to\[O_{2}^{2-}\]

    C)  Fe is oxidised to\[F{{e}^{2+}}\]and\[{{H}_{2}}O\]is reduced to

    D)  Fe is oxidised to\[F{{e}^{2+}}\]and\[{{H}_{2}}O\]is reduced to\[{{O}_{2}}\]

    Correct Answer: A

    Solution :

                    \[Fe\xrightarrow[{}]{{}}F{{e}^{2+}}+2{{e}^{-}}\]                     (anode reaction) \[{{O}_{2}}+2{{H}_{2}}O+4{{e}^{-}}\xrightarrow[{}]{{}}4O{{H}^{-}}\]            (cathode reaction) The overall reaction is \[2Fe+{{O}_{2}}+2{{H}_{2}}\text{O}\xrightarrow{{}}2Fe{{(OH)}_{2}}\] \[Fe{{(OH)}_{2}}\]may be dehydrated to iron oxide \[FeO\]. or further oxidised of\[Fe{{(OH)}_{3}}\]and then dehydrated to iron rust,\[F{{e}_{2}}{{O}_{3}}\].


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