Manipal Medical Manipal Medical Solved Paper-2006

  • question_answer
    Solubility product of\[BaC{{l}_{2}}\]is\[4\times {{10}^{-9}}\]. Its solubility would be:

    A)  \[1\times {{10}^{-27}}\]

    B)  \[1\times {{10}^{-3}}\]

    C)  \[1\times {{10}^{-7}}\]

    D)  \[1\times {{10}^{-2}}\]

    Correct Answer: B

    Solution :

     \[BaC{{l}_{2}}\]is a ternary electrolyte. \[BaC{{l}_{2}}=\underset{s}{\mathop{B{{a}^{2+}}}}\,+\underset{2s}{\mathop{2C{{l}^{-}}}}\,\] \[{{K}_{sp}}=[B{{a}^{2+}}]+{{[2C{{l}^{-}}]}^{2}}\] \[=[s]{{[2s]}^{2}}\] \[{{K}_{sp}}=4{{s}^{3}}\] \[{{K}_{sp}}=4{{s}^{3}}\]where\[s=\]molar solubility \[4{{s}^{3}}=4\times {{10}^{-9}}\] (given) or  \[s={{10}^{-3}}M\]


You need to login to perform this action.
You will be redirected in 3 sec spinner