Manipal Medical Manipal Medical Solved Paper-2002

  • question_answer
    The isomerism represented by ethyl acetoacetate is:

    A)  keto-enol isomerism

    B)  geometrical isomerism

    C)  enantiomerism

    D)  diasterioisomerism

    Correct Answer: A

    Solution :

     Ethyl acetoacetate represents keto-enol isomerism. \[\underset{Keto\,form}{\mathop{C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  |\,\,| \end{smallmatrix}}{\mathop{C}}\,}}\,-\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}\,HCOO{{C}_{2}}{{H}_{5}}\] \[\underset{Enolic\text{ }form}{\mathop{C{{H}_{3}}-\overset{\begin{smallmatrix}  OH \\  | \end{smallmatrix}}{\mathop{C}}\,}}\,=CHCOO{{C}_{2}}{{H}_{5}}\]


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