Manipal Engineering Manipal Engineering Solved Paper-2013

  • question_answer
    \[0.01M\]solution of\[KCl\]and\[CaC{{l}_{2}}\]are prepared in water. The freezing point of\[KCl\]is found to be\[-{{2}^{o}}C\]. What is the freezing point of\[CaC{{l}_{2}}\]to be completely ionised?

    A) \[-{{3}^{o}}C\]

    B) \[+{{3}^{o}}C\]

    C) \[-{{2}^{o}}C\]  

    D)        \[-{{4}^{o}}C\]

    Correct Answer: A

    Solution :

                                    \[i\]for\[KCl=2,\]for for\[CaC{{L}_{2}}=3\], \[\Delta {{T}_{f}}\propto i\] \[\frac{\Delta {{T}_{f}}(KCl)}{\Delta {{T}_{f}}(CaC{{l}_{2}})}=\frac{2}{3}\] \[\Delta {{T}_{f}}(CaC{{l}_{2}})=\frac{3}{2}\times 2={{3}^{o}}C\] Freezing point of\[CaC{{l}_{2}}={{3}^{o}}C\]


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