Manipal Engineering Manipal Engineering Solved Paper-2010

  • question_answer
    \[E{}^\circ \]values of\[M{{g}^{2+}}/Mg\]is\[-2.37\,\,V\]of\[Z{{n}^{2+}}/Zn\]is\[-0.76\,\,V\] and\[F{{e}^{2+}}/Fe\]is\[-0.44\,\,V\]. Which of the statements is correct?

    A) \[Zn\]will reduce\[F{{e}^{2+}}\]

    B) \[Zn\]will reduce\[M{{g}^{2+}}\]

    C) \[Mg\]oxidizes\[Fe\]

    D) \[Zn\]oxidizes\[Fe\]

    Correct Answer: A

    Solution :

    Higher the negative value of\[E{}^\circ \], more is the reducing power. The order of\[E{}^\circ \]values (negative value) is                 \[-\underset{(Mg)}{\mathop{2.37}}\,>-\underset{(Zn)}{\mathop{0.76}}\,>\underset{(Fe)}{\mathop{-0.44}}\,\] \[\therefore \]\[Mg\]can reduce both\[Z{{n}^{2+}}\]and\[F{{e}^{2+}}\].\[Zn\]can reduce\[F{{e}^{2+}}\], but not\[M{{g}^{2+}}\]. Fe cannot reduce \[Mg\]and\[~Zn\]but can oxidize them.


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