Manipal Engineering Manipal Engineering Solved Paper-2010

  • question_answer
    Which one of the following compounds will dissolve in an alkali solution after it has undergone reaction with Hinsberg reagent?

    A) \[C{{H}_{3}}N{{H}_{2}}\]                              

    B) \[{{(C{{H}_{3}})}_{3}}N\]             

    C)        \[{{({{C}_{2}}{{H}_{5}})}_{2}}NH\]           

    D)        \[{{C}_{6}}{{H}_{5}}NH{{C}_{6}}{{H}_{5}}\]

    Correct Answer: A

    Solution :

    \[\underset{1{}^\circ \text{amine}}{\mathop{C{{H}_{3}}N{{H}_{2}}}}\,+\underset{\begin{smallmatrix}  Hinsbergs \\  reagent \end{smallmatrix}}{\mathop{{{C}_{6}}{{H}_{5}}S{{O}_{2}}Cl}}\,\xrightarrow{{}}\underset{\begin{smallmatrix}  N-methyl\,\,benzene \\  sulphonamide \end{smallmatrix}}{\mathop{{{C}_{6}}{{H}_{5}}S{{O}_{2}}NHC{{H}_{3}}}}\,\]                              \[\xrightarrow[(alkali)]{NaOH}{{C}_{6}}{{H}_{5}}S{{O}_{2}}N(Na)C{{H}_{3}}\]


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