A) \[C{{H}_{3}}OH\]
B) \[C{{H}_{4}}\]
C) \[C{{H}_{3}}COON{{H}_{4}}\]
D) \[C{{H}_{3}}CN\]
Correct Answer: D
Solution :
\[C{{H}_{3}}COOH\xrightarrow{N{{H}_{3}}}C{{H}_{3}}\underset{(A)}{\mathop{-}}\,\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,-\overset{-}{\mathop{O}}\,\overset{\oplus }{\mathop{N}}\,{{H}_{4}}\] \[\xrightarrow[-{{H}_{2}}O]{Heat}C{{H}_{3}}\underset{\begin{smallmatrix} (B) \\ acetamide \end{smallmatrix}}{\mathop{-}}\,\overset{\begin{smallmatrix} O \\ || \end{smallmatrix}}{\mathop{C}}\,-N{{H}_{2}}\xrightarrow[\Delta ]{{{P}_{4}}{{O}_{10}}}\] \[C{{H}_{3}}\underset{\begin{align} & (C) \\ & acetonitrile \\ & or \\ & methyl\,\,cyanide \\ \end{align}}{\mathop{-}}\,C\equiv N\]
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