JEE Main & Advanced JEE Main Solved Paper-2015

  • question_answer
    The standard Gibbs energy change at 300K for the reaction \[2AB+C\]At a given time, the composition of the reaction mixture is\[\left[ A \right]=\frac{1}{2},\left[ B \right]=2\]and \[\left[ C \right]=\frac{1}{2}.\]  The reaction proceeds in the : \[[R=8.314J/Kmol,e=2.718]\] [JEE Main Solved Paper-2015 ]

    A) forward direction because \[Q<{{K}_{C}}\]

    B) reverse direction because \[Q<{{K}_{C}}\]

    C) forward direction because \[Q>{{K}_{C}}\]

    D) reverse direction beacuse \[Q>{{K}_{C}}\]

    Correct Answer: D

    Solution :

    \[Q=\frac{\left[ B \right]\left[ C \right]}{{{\left[ A \right]}^{2}}}=\frac{2\times \frac{1}{2}}{\frac{1}{2}\times \frac{1}{2}}=4\] \[\Delta {{G}^{0}}=-2.303RT\log {{K}_{eq}}\] \[2494.2=-2.303\times 8.314\times 300\times \log K\] \[-\log K=0.434\] \[\log \frac{1}{K}=0.434\] \[\frac{1}{K}=2.7\] \[K=\frac{1}{2.7}=0.37\] \[\therefore \]\[Q>K\] \[\therefore \] Backward reaction favoured i.e. reverse direction


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