JEE Main & Advanced JEE Main Paper (Held On 9 April 2014)

  • question_answer
    In which of the following pairs A is more stable than B?   [JEE Main Online Paper ( Held On 09 Apirl  2014  )

    A)

    B)

    C)

    D) \[P{{h}_{3}}{{C}^{\bullet }},{{(C{{H}_{3}})}_{3}}{{C}^{\bullet }}\]

    Correct Answer: D

    Solution :

    \[P{{h}_{3}}\overset{.}{\mathop{C}}\,\]is more stable than \[{{(C{{H}_{3}})}_{3}}\overset{.}{\mathop{C}}\,\]because resonance stabilisation effect in \[P{{h}_{3}}\overset{.}{\mathop{C}}\,\] is more pronounced as compared to hyper conjugation stabilization effect in \[{{(C{{H}_{3}})}_{3}}\overset{.}{\mathop{C}}\,\]overall stability order among free radical is : Triphenylmethyl> benzyl >allyl> tertiary alkyl > secondary > primary > methyl > vinyl


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