JEE Main & Advanced JEE Main Paper (Held On 19 April 2014)

  • question_answer
    Which one of the following substituents at para-position is most effective in stabilizing the phenoxide O - ion?     JEE Main Online Paper (Held On 19 April 2016)

    A) \[-C{{H}_{3}}\]                 

    B) \[-OC{{H}_{3}}\]

    C) \[-COC{{H}_{3}}\]           

    D) \[-C{{H}_{2}}OH\]

    Correct Answer: C

    Solution :

    Electron withdrawing group stabilises the benzene ring due to delocalisation of charge. \[-C{{H}_{3}}\]and \[-C{{H}_{2}}OH\]are electron donating group and hence decrease the stability of benzene ring \[-OC{{H}_{3}}\] is weaker electron withdrawing group than \[-COC{{H}_{3}}.\] Hence \[-COC{{H}_{3}}\] group more stabilize the phenoxide ion at p-position.


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