JEE Main & Advanced JEE Main Online Paper (Held On 23 April 2013)

  • question_answer
                    Identify the incorrect statement:     JEE Main Online Paper ( Held On 23  April 2013 )

    A)                   In\[{{(\operatorname{S}{{\operatorname{i}}_{3}}{{\operatorname{O}}_{9}})}^{6-}}\], tetrahedral \[Si{{O}_{4}}\] units share two oxygen atoms.

    B)                                         Trialkylchlorosilaneon hydrolysis gives \[{{R}_{3}}SiOH\]

    C)                                         \[SiC{{l}_{4}}\]undergoes hydrolysis to give \[{{H}_{4}}Si{{O}_{4}}\]

    D)                                         \[{{(\operatorname{S}{{\operatorname{i}}_{3}}{{\operatorname{O}}_{9}})}^{6-}}\]has cyclic structure

    Correct Answer: B

    Solution :

                      The hydrolysis of Trialkylchlorosilane \[{{R}_{3}}SiCl\]yields dimer: \[R-\underset{\begin{smallmatrix}  | \\  R \end{smallmatrix}}{\overset{\begin{smallmatrix}  R \\  | \end{smallmatrix}}{\mathop{Si}}}\,-O-\underset{\begin{smallmatrix}  | \\  R \end{smallmatrix}}{\overset{\begin{smallmatrix}  R \\  | \end{smallmatrix}}{\mathop{Si}}}\,-R\]


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