Solved papers for NEET Chemistry Concepts of Acids & Bases NEET PYQ-Concepts Of Acids Bases

done NEET PYQ-Concepts Of Acids Bases Total Questions - 26

  • question_answer1) How many gram of dibasic acid (mol. wt. 200) should be present in 100 mL of the aqueous solution to give 0.1 N?                    [AIPMT 1999]

    A)
     1 g   

    B)
                      2 g                  

    C)
     10 g    

    D)
                     20 g

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  • question_answer2) The strongest conjugate base is:                                                                                          [AIPMT 1999]

    A)
     \[NO_{3}^{-}\]                       

    B)
    \[C{{l}^{-}}\] 

    C)
     \[SO_{4}^{2-}\]     

    D)
               \[C{{H}_{3}}CO{{O}^{-}}\]

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  • question_answer3) The conjugate acid of \[NH_{2}^{-}\] is:                                                                                      [AIPMT 2000]

    A)
     \[{{N}_{2}}{{H}_{4}}\]         

    B)
    \[NH_{4}^{+}\]          

    C)
     \[N{{H}_{2}}OH\] 

    D)
     \[N{{H}_{3}}\]

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  • question_answer4) In \[H{{S}^{-}},\,\,{{I}^{-}},\,\,RN{{H}_{2}},\,\,N{{H}_{3}}\] order of proton accepting tendency will be:       [AIPMT 2001]

    A)
     \[{{I}^{-}}>N{{H}_{3}}>RN{{H}_{2}}>H{{S}^{-}}\]

    B)
                      \[N{{H}_{3}}>RN{{H}_{2}}>H{{S}^{-}}>{{I}^{-}}\]

    C)
     \[RN{{H}_{2}}>N{{H}_{3}}>H{{S}^{-}}>{{I}^{-}}\]

    D)
                      \[H{{S}^{-}}>RN{{H}_{2}}>N{{H}_{3}}>{{I}^{-}}\]

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  • question_answer5) Which of the following order is wrong?                                                                   [AIPMT 2002]

    A)
           \[N{{H}_{3}}<\text{ }P{{H}_{3}}<\text{ }As{{H}_{3}}\]acidic

    B)
                      \[Li<Be<B<C-\]1st IP

    C)
     \[A{{I}_{2}}{{O}_{3}}<MgO<N{{a}_{2}}O<{{K}_{2}}O\]basic

    D)
          \[L{{i}^{+}}<N{{a}^{+}}<{{K}^{+}}<C{{s}^{+}}-\]ionic radius

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  • question_answer6) Which one of the following orders of acid strength is correct?                                      [AIPMT 2003]

    A)
    \[RCOOH>HOH>HC~CH>ROH\]        

    B)
          \[RCOOH>HC~CH>HOH>ROH\]

    C)
     \[RCOOH>ROH>HOH>HC~CH\]       

    D)
     \[RCOOH>HOH>ROH>HC~CH\]

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  • question_answer7) Which is the best description of behaviour of bromine in the reaction given below\[{{H}_{2}}O+B{{r}_{2}}\xrightarrow[{}]{{}}HBr+HOBr\]                                   [AIPMT (S) 2004]

    A)
     Proton accepted only

    B)
     Both oxidised and reduced

    C)
     Oxidised only

    D)
     Reduced only

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  • question_answer8) The correct order of acid strength is:                                                                                  [AIPMT (S) 2005]

    A)
     \[HClO<HCl{{O}_{2}}<HCl{{O}_{3}}<HCI{{O}_{4}}\]

    B)
                \[HCl{{O}_{4}}<HClO<HCl{{O}_{2}}<HCl{{O}_{3}}\]

    C)
     \[HCl{{O}_{2}}<HCl{{O}_{3}}<HCl{{O}_{4}}<HClO\]

    D)
     \[HCl{{O}_{4}}<HCl{{O}_{3}}<HCl{{O}_{2}}<HClO\]

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  • question_answer9) Which of the following is not a correct statement?                                                                [AIPMT (S) 2006]

    A)
           The electron-deficient molecules can act as Lewis acids

    B)
     The canonical structures have no real existence

    C)
          Every AB5 molecule does in fact have square pyramid structure

    D)
          Multiple bonds are always shorter than corresponding single bonds

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  • question_answer10) Which one of the following orders is not in accordance with the property stated against it?        [AIPMT (S) 2006]

    A)
           \[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\]Oxidising power      

    B)
    \[HI>HBr>HCI>HF:\]Acidic property in water

    C)
          \[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\]Electronegativity

    D)
          \[{{F}_{2}}>C{{l}_{2}}>B{{r}_{2}}>{{I}_{2}}:\] Bond dissociation energy

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  • question_answer11) Which of die following represents the correct order of the acidity in the given compounds?         [AIPMT (S) 2007]

    A)
     \[C{{H}_{3}}COOH>BrC{{H}_{2}}COOH>ClC{{H}_{2}}COOH\] \[>FC{{H}_{2}}COOH\]

    B)
          \[FC{{H}_{2}}COOH>C{{H}_{3}}COOH>BrC{{H}_{2}}COOH\]\[>ClC{{H}_{2}}COOH\]

    C)
          \[BrC{{H}_{2}}COOH>CIC{{H}_{2}}COOH>FC{{H}_{2}}COOH\]\[>C{{H}_{3}}COOH\]

    D)
          \[FC{{H}_{2}}COOH>ClC{{H}_{2}}COOH>BrC{{H}_{2}}COOH\]\[>C{{H}_{3}}COOH\]

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  • question_answer12) Which one of the following ionic species has the greatest proton affinity to form stable compound?        [AIPMT (S) 2007]

    A)
     \[H{{S}^{-}}\]

    B)
                      \[NH_{2}^{-}\]

    C)
     \[{{F}^{-}}\]  

    D)
                      \[{{I}^{-}}\]

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  • question_answer13) Which one of the following orders correctly represents the increasing acid strengths of the given acids?    [AIPMT (S) 2007]

    A)
     \[HOCl<HOClO<HOCl{{O}_{2}}<HOCl{{O}_{3}}\]

    B)
     \[HOClO<HOCl<HOCl{{O}_{3}}<HOCI{{O}_{2}}\]

    C)
     \[HOCl{{O}_{2}}<HOCl{{O}_{3}}<HOClO<HOCl\]

    D)
     \[HOCl{{O}_{3}}<HOCl{{O}_{2}}<HOClO<HOCl\]

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  • question_answer14) 
    Base strength of                                                                                                          [AIPMT (S) 2008]
    (1) \[{{H}_{3}}C\overset{\Theta }{\mathop{C}}\,{{H}_{2}}\]                
    (2) \[{{H}_{2}}C=\overset{\Theta }{\mathop{C}}\,H\]and
    (3) \[H-C\equiv \overset{\Theta }{\mathop{C}}\,\] is in the order of

    A)
     (2) > (1) > (3)  

    B)
          (3) > (2) > (1)

    C)
     (1) > (3) > (2)             

    D)
     (1) > (2) > (3)

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  • question_answer15) Which of the following molecules acts as a Lewis acid?                                                          [AIPMT (S) 2009]

    A)
     \[{{(C{{H}_{3}})}_{3}}B\]     

    B)
          \[{{(C{{H}_{3}})}_{2}}O\]

    C)
     \[{{(C{{H}_{3}})}_{2}}P\]     

    D)
          \[{{(C{{H}_{3}})}_{3}}N\]

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  • question_answer16) Which one of the following molecular hydrides acts as a Lewis acid?                                        [AIPMT (S) 2010]

    A)
     \[N{{H}_{3}}\]           

    B)
          \[{{H}_{2}}O\]

    C)
     \[{{B}_{2}}{{H}_{6}}\]         

    D)
          \[C{{H}_{4}}\]

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  • question_answer17) Which of the following is least likely to behave as Lewis base?                                                 [AIPMT (S) 2011]

    A)
     \[N{{H}_{3}}\]           

    B)
          \[B{{F}_{3}}\]                         

    C)
     \[O{{H}^{-}}\]       

    D)
     \[{{H}_{2}}O\]

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  • question_answer18) The correct order of decreasing acid strength of trichloroacedc acid , trifluoroacetic acid, acetic acid  and formic acid  is                                                                                                                          [AIPMT (S) 2012]

    A)
     B > A > D > C

    B)
        B > D > C > A

    C)
     A > B > C > D 

    D)
          A > C > B > D

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  • question_answer19) In which of the following arrangements the given sequence is not strictly according to the property indicated against it?         [AIPMT (M) 2012]

    A)
     \[HF<HCl<HBr,HI:\] increasing acidic strength

    B)
    \[{{H}_{2}}O<{{H}_{2}}S<{{H}_{2}}Se<{{H}_{2}}Te:\] increasing \[p{{K}_{a}}\] values

    C)
     \[N{{H}_{3}}<p{{H}_{3}}<As{{H}_{3}}<Sb{{H}_{3}}:\] increasing acidic character

    D)
     \[C{{O}_{2}}<Si{{O}_{2}}<Sn{{O}_{2}}<Pb{{O}_{2}}\]: increasing oxidising power

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  • question_answer20) Which is the strongest acid in the following?                                                                                    [NEET 2013]

    A)
     \[{{H}_{2}}S{{O}_{4}}\]       

    B)
         \[HCl{{O}_{3}}\]         

    C)
     \[HCl{{O}_{4}}\]        

    D)
          \[{{H}_{2}}S{{O}_{3}}\]

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  • question_answer21)   Which of these is least likely to act as a Lewis base?                                                                                    [NEET 2013]

    A)
     CO                 

    B)
         \[{{F}^{-}}\]               

    C)
     \[B{{F}_{3}}\]            

    D)
          \[P{{F}_{3}}\]

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  • question_answer22) Acidity of diprotic acids in aqueous solutions increases in the order                                         [AIPMT 2014]

    A)
     \[{{H}_{2}}S<{{H}_{2}}Se<{{H}_{2}}Te\]

    B)
          \[{{H}_{2}}Se<{{H}_{2}}S<{{H}_{2}}Te\]

    C)
     \[{{H}_{2}}Te<{{H}_{2}}S<{{H}_{2}}Se\]

    D)
          \[{{H}_{2}}Se<{{H}_{2}}Te<{{H}_{2}}S\]

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  • question_answer23) Among the following, the correct order of acidity is                                                                          [NEET - 2016]

    A)
     \[HCl{{O}_{3}}<HCl{{O}_{4}}<HCl{{O}_{2}}<HClO\]

    B)
     \[~HClO<HCl{{O}_{2}}<HCl{{O}_{3}}<HCl{{O}_{4}}\]

    C)
     \[HCl{{O}_{2}}<HClO<HCl{{O}_{3}}<HCl{{O}_{4}}\]

    D)
     \[HCl{{O}_{4}}<HCl{{O}_{2}}<HClO<HCl{{O}_{3}}\]

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  • question_answer24) Which one is the correct order of acidity?                                                                     [NEET-2017]

    A)
     \[C{{H}_{3}}=C{{H}_{3}}>C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-C\]\[=CH>CH=CH\]

    B)
     \[C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-CH=C{{H}_{2}}>C{{H}_{3}}-C\]\[\equiv CH>CH\equiv CH\]

    C)
     \[CH\equiv CH>C{{H}_{3}}-C\equiv CH>C{{H}_{2}}\]\[=C{{H}_{2}}>C{{H}_{3}}-C{{H}_{3}}\]

    D)
     \[CH\equiv CH>C{{H}_{2}}=C{{H}_{2}}>C{{H}_{3}}-C\]\[\equiv CH>C{{H}_{3}}-C{{H}_{3}}\]

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  • question_answer25) Conjugate base for Bronsted acids \[{{H}_{2}}O\]and HF are:                                            [NEET 2019]

    A)
     \[O{{H}^{}}\]and\[{{F}^{}}\], respectively

    B)
     \[{{H}_{3}}{{O}^{+}}\]and\[{{H}_{2}}{{F}^{+}}\], respectively

    C)
     \[O{{H}^{}}\]and\[{{H}_{2}}{{F}^{+}}\], respectively

    D)
     \[{{H}_{3}}{{O}^{+}}\]and\[{{F}^{}}\], respectively

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  • question_answer26) Which will make basic buffer?                                                                                           [NEET 2019]

    A)
     \[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }HCl+200\text{ }mL\text{ }of\text{ }\]\[0.1M\text{ }N{{H}_{4}}OH\]

    B)
    \[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }HCl+100\text{ }mL\text{ }of\text{ }\]\[0.1\text{ }M\text{ }NHOH\]

    C)
     \[50\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }NaOH+25\text{ }mL\text{ }of\]\[0.1\text{ }M\text{ }C{{H}_{3}}COOH\]

    D)
     \[100\text{ }mL\text{ }of\text{ }0.1\text{ }M\text{ }C{{H}_{3}}COOH+100\]\[mL\text{ }of\text{ }0.1\text{ }M\text{ }NaOH\]

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