JCECE Medical JCECE Medical Solved Paper-2011

  • question_answer
    Anti-Markowhikoffs addition of HBr is not observed in

    A) propene          

    B)  1-butene  

    C)  but-2-ene         

    D)  pent-2-ene

    Correct Answer: C

    Solution :

     Anti-Markownikoffs rule is not applicable case of symmetrical alkenes. The structures of the given compounds are \[\underset{\text{propene}}{\mathop{C{{H}_{3}}CH=C{{H}_{2}}}}\,\]\[\underset{1-\text{butene}}{\mathop{C{{H}_{3}}C{{H}_{2}}CH=C{{H}_{2}}}}\,\] \[\underset{\begin{smallmatrix}  \text{but}-2-\text{ene} \\  (symmetrical) \end{smallmatrix}}{\mathop{C{{H}_{3}}CH=CHC{{H}_{3}}}}\,\]\[\underset{\text{pent}-2-\text{ene}}{\mathop{C{{H}_{3}}C{{H}_{2}}CH=CHC{{H}_{3}}}}\,\] Thus, anti-Markownikoffs rule is not applicable to but-2-ene.


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