JCECE Medical JCECE Medical Solved Paper-2008

  • question_answer
    An aqueous solution of 6.3 g of oxalic acid dihydrate is made upto 250 mL. The volume of  \[\text{0}\text{.1}\,\text{N}\,\text{NaOH}\]required to completely neutralize 10 mL of this solution is

    A)  \[\text{40 mL}\]

    B)  \[\text{20 mL}\]

    C)  \[10\,mL\]

    D)  \[4\,mL\]

    Correct Answer: A

    Solution :

     Equivalent weight of oxalic acid\[~=126/2\] (\[\because \]Basicity of oxalic acid\[=2\]) Normality of oxalic acid solution \[=\frac{6.3\times 1000}{63\times 250}\] \[=0.4\,N\] \[\underset{(Acid)}{\mathop{{{N}_{1}}{{V}_{1}}}}\,=\underset{(Base)}{\mathop{{{N}_{2}}{{V}_{2}}}}\,\] \[0.4\times 10\,mL=0.1\times {{V}_{2}}\] \[{{V}_{2}}=40\,mL\]


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