JCECE Medical JCECE Medical Solved Paper-2008

  • question_answer
    \[\text{NaCl,}\,\text{NaBr}\]and \[\text{NaI}\]mixture on heating with  cone. \[{{\text{H}}_{\text{2}}}\text{S}{{\text{O}}_{\text{4}}}\]gives gases, respectively

    A) \[HCl,HBr,HI\]

    B) \[HCl,B{{r}_{2}},{{I}_{2}}\]

    C)  \[C{{l}_{2}},B{{r}_{2}},{{I}_{2}}\]

    D) \[C{{l}_{2}},HBr,HI\]

    Correct Answer: B

    Solution :

     \[NaCl+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }NaHS{{O}_{4}}+HCl\uparrow \] \[HCl+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }\text{No}\,\text{reactioin}\] \[NaBr+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }NaHS{{O}_{4}}+HBr\] \[2HBr+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }B{{r}_{2}}\uparrow +S{{O}_{2}}+2{{H}_{2}}O\] \[NaI+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }NaHS{{O}_{4}}+HI\] \[2HI+{{H}_{2}}S{{O}_{4}}\xrightarrow{\Delta }{{I}_{2}}\uparrow +S{{O}_{2}}+2{{H}_{2}}O\] Hence, the gases released are \[\text{HCl,}\,\text{B}{{\text{r}}_{\text{2}}}\]and \[{{\text{I}}_{2}}.\]


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