JCECE Medical JCECE Medical Solved Paper-2002

  • question_answer
    \[A+NaOH\xrightarrow{{}}C{{H}_{3}}OH+HCOONa\]is the reaction, compound A is:

    A)  HCN        

    B)  HCHO

    C)  \[C{{H}_{3}}CN\]

    D) \[C{{H}_{3}}Cl\]

    Correct Answer: B

    Solution :

     Key Idea: This is Cannizaro reaction. In this reaction aldehydes, which do not have \[\alpha -\]hydrogen atom undergo disproportionation reaction, half of the, molecule are reduced and other half are oxidised. \[\underset{(A)}{\mathop{HCHO}}\,\,+NaOH\xrightarrow{{}}\underset{\text{sodium}\,\text{formate}}{\mathop{HCOONa}}\,\,+\,\underset{\text{methyl}\,\text{alcohol}}{\mathop{C{{H}_{3}}OH}}\,\]


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