JCECE Engineering JCECE Engineering Solved Paper-2012

  • question_answer
    \[C{{e}^{4+}}\] is stable. This is because

    A)  half-filled \[d-\]orbitals

    B)  all paired electrons in \[d-\]orbitals

    C)  empty \[d-\]orbitals

    D)  fully filled \[d-\]orbitals

    Correct Answer: C

    Solution :

    \[Ce(58)=[Xe]4{{f}^{1}}5{{d}^{1}}6{{s}^{2}}\]predicted \[[Xe]4{{f}^{2}}5{{d}^{0}}6{{s}^{2}}\]observed \[C{{e}^{4+}}=[Xe]4{{f}^{0}}5{{d}^{0}}6{{s}^{0}}\] Since, in \[+4\] oxidation state, all orbitals are empty and it gains the stable configuration of nearest inert gas, therefore \[C{{e}^{4+}}\] is most stable.


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