JCECE Engineering JCECE Engineering Solved Paper-2010

  • question_answer
    A solution contains \[10\,\,mL\] \[0.1\,\,N\,\,NaOH\] and NH\[10\,\,mL\,\,0.05\,\,N\,\,{{H}_{2}}S{{O}_{4}}\], \[pH\] of this solution is

    A)  less than\[7\]                  

    B) \[7\]

    C)   zero                                    

    D)   greater than\[7\]

    Correct Answer: B

    Solution :

    Given, for\[NaOH,\,\,V=10\,\,mL,\,\,N=0.1\,\,N\] For\[{{H}_{2}}S{{O}_{4}},\,\,V=10\,\,mL,\,\,N=0.05\,\,N\] Miliequivalents of\[NaOH=10\times 0.1=1\] Miliequivalents of\[{{H}_{2}}S{{O}_{4}}=10\times 0.05=0.5\] \[\underset{1\,\,equivalent}{\mathop{{{H}_{2}}S{{O}_{4}}}}\,+\underset{2\,\,equivalent}{\mathop{2NaOH}}\,\xrightarrow{{}}N{{a}_{2}}S{{O}_{4}}+{{H}_{2}}O\] \[\because \]\[0.5\] equivalent of \[{{H}_{2}}S{{O}_{4}}\] will react with 1 equivalent of\[NaOH\] \[\therefore \]The pH of solution\[=7\] (neutral)


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