JCECE Engineering JCECE Engineering Solved Paper-2008

  • question_answer
    The concentration of \[{{H}_{2}}{{O}_{2}}\] solution of \['10\] volume' is

    A) \[30%\]                               

    B) \[3%\]

    C) \[1%\]                                  

    D)  \[10%\]

    Correct Answer: B

    Solution :

    \[''10\]volume\[{{H}_{2}}{{O}_{2}}''\] means \[1\,\,mL\] of its solution on decomposition at\[NTP\], give \[10\,\,mL\] oxygen gas. Volume of oxygen formed from \[100\,\,mL\] of solution at\[NTP=1000\,\,mL\],                 \[\underset{\begin{smallmatrix}  2\,\,mol \\  2\times 34\,\,g \end{smallmatrix}}{\mathop{2{{H}_{2}}{{O}_{2}}}}\,\xrightarrow[{}]{{}}2{{H}_{2}}O+\underset{\begin{smallmatrix}  1\,\,mol \\  22400\,\,mL \end{smallmatrix}}{\mathop{{{O}_{2}}}}\,\] \[\because \]\[22400\,\,m\,\,L\,\,{{O}_{2}}\] formed at \[NTP\] by decomposition of.\[68\,\,g\,\,{{H}_{2}}{{O}_{2}}\]. \[\therefore \]\[1mL\,\,{{O}_{2}}\] formed at \[NTP\] from\[\frac{68}{22400}g\]of\[{{H}_{2}}{{O}_{2}}\] \[\therefore \]\[1000\,\,mL\,\,{{O}_{2}}\]formed at \[NTP\] from                 \[\frac{68\times 1000}{22400}g\,\,{{H}_{2}}{{O}_{2}}=3.035\,\,g\,\,{{H}_{2}}{{O}_{2}}\] So, concentration of \[''10\]volume\[{{H}_{2}}{{O}_{2}}''\] \[=3.0%\]approximately


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