JCECE Engineering JCECE Engineering Solved Paper-2008

  • question_answer
    In acidic medium dichromate ion oxidises ferrous ion to ferric ion. If gram molecular weight of potassium dichromate is \[294\,\,g\], its gram equivalent weight is

    A) \[294\,\,g\]                        

    B) \[127\,\,g\]

    C)  \[49\,\,g\]                         

    D)  \[24.5\,\,g\]

    Correct Answer: C

    Solution :

    \[C{{r}_{2}}O_{7}^{2-}+14{{H}^{+}}+6{{e}^{-}}\xrightarrow{{}}2C{{r}^{3+}}+7{{H}_{2}}O\] Gram eq. wt. \[=\frac{Gram\,\,molecular\,\,weight}{Change\,\,in\,\,oxidation\,\,numper\,\,per\,\,atom}\] Gram eq. wt.\[=\frac{294}{6}\]                         \[=49\,\,g\]


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