JCECE Engineering JCECE Engineering Solved Paper-2006

  • question_answer
    \[S+\frac{3}{2}{{O}_{2}}\xrightarrow{{}}S{{O}_{3}}\Delta H=2x\],\[S{{O}_{2}}+\frac{1}{2}{{O}_{2}}\xrightarrow{{}}S{{O}_{3}}\Delta H=y\],then heat of formation of \[S{{O}_{2}}\] is:

    A) \[2x-y\]                               

    B) \[2x+y\]

    C) \[x+y\]                

    D) \[\frac{2x-y}{2}\]

    Correct Answer: A

    Solution :

    Given: \[S+\frac{3}{2}{{O}_{2}}\xrightarrow{{}}S{{O}_{3}}\]       \[\Delta n=2x\] ... (i) \[S{{O}_{2}}+\frac{1}{2}{{O}_{2}}\xrightarrow{{}}S{{O}_{3}}\]     \[\Delta n=y\]                   ... (ii) Heat of formation of \[S{{O}_{2}}\] can be calculated by reversing the Eq. (ii) and then adding the Eq. (i) and (iii).                 \[S{{O}_{3}}\xrightarrow{{}}S{{O}_{2}}+\frac{1}{2}{{O}_{2}}-y\] ... (iii) Now, by adding the Eqs. (i) and (ii)                 \[S+\frac{3}{2}{{O}_{2}}\xrightarrow{{}}S{{O}_{3}}+2x\]                                ... (i)                 \[S{{O}_{3}}\xrightarrow{{}}S{{O}_{2}}+\frac{1}{2}{{O}_{2}}-y\] ... (ii)                 \[\underline{\overline{S+{{O}_{2}}\xrightarrow{{}}S{{O}_{2}}+(2x-y)}}\]               ... (iii) So, heat of formation of \[S{{O}_{2}}\] is\[2x-y\].


You need to login to perform this action.
You will be redirected in 3 sec spinner