JCECE Engineering JCECE Engineering Solved Paper-2003

  • question_answer
    In the reaction, product \['X'\] is: \[C{{H}_{3}}-C\equiv CH+{{H}_{2}}O\xrightarrow{{{H}^{+}}/H{{g}^{2+}}}X\]

    A) \[C{{H}_{3}}C{{H}_{2}}CHO\]

    B) \[C{{H}_{3}}C{{H}_{2}}COOH\]

    C) \[C{{H}_{3}}-C(OH)=CHOH\]

    D)  \[C{{H}_{3}}COC{{H}_{3}}\]

    Correct Answer: D

    Solution :

    Key Idea: \[{{H}_{2}}O\] adds across triple bond in presence of \[H{{g}^{2+}}\] salt. \[\underset{propyne-1}{\mathop{C{{H}_{3}}-C\equiv CH+{{H}_{2}}O}}\,\xrightarrow{{{H}^{+}}/H{{g}^{2+}}}\] \[\underset{acetone}{\mathop{C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}}}\,\]


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