JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2011

  • question_answer
        \[Ge(II)\]compounds are more powerful reducing agents whereas\[Pb(IV)\]compounds are strong oxidants. It can be due to

    A) \[Pb\]is more electropositive than\[Ge\]

    B)  ionisation potential of lead is less than that of\[Ge\]

    C)  ionic radii of\[P{{b}^{2+}}\]and\[P{{b}^{4+}}\]are larger than those of\[G{{e}^{2+}}\]and\[G{{e}^{4+}}\]

    D)  more pronounced inert pair effect in lead than in Ge

    Correct Answer: D

    Solution :

                    \[Ge(IV)\]is more stable than\[Ge(II)\]. Therefore, \[Ge(II)\]compounds are powerful reducing agents.\[Pb(IV)\]is less stable than\[Pb(II)\]. Therefore,\[Pb(IV)\]compounds are powerful oxidising agents. This is due to inert pair effect, due to which the +2 oxidation state becomes more stable on moving down the group.


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